食品科学 ›› 2017, Vol. 38 ›› Issue (24): 137-143.doi: 10.7506/spkx1002-6630-201724022

• 成分分析 • 上一篇    下一篇

元宝枫种仁70%乙醇提取物的化学成分分析

张玉伟,李珊珊,宋明杰,陈建波,刘畅,张磊,李岱龙,孙印石   

  1. (1.中国农业科学院特产研究所,吉林?长春 130112;2.山东永春堂集团有限公司,山东?泗水 273299)
  • 出版日期:2017-12-25 发布日期:2017-12-07
  • 基金资助:
    吉林省医药健康产业发展引导资金项目(20150311055YY;201603078YY)

Chemical Constituents of 70% EtOH Extract from the Kernel of Acer truncatum Bunge

ZHANG Yuwei, LI Shanshan, SONG Mingjie, CHEN Jianbo, LIU Chang, ZHANG Lei, LI Dailong, SUN Yinshi   

  1. (1. Institute of Special Animal and Plant Sciences, Chinese Academy of Agricultural Sciences, Changchun 130112, China; 2. Shandong Yongchun Church Group Co. Ltd., Sishui 273299, China)
  • Online:2017-12-25 Published:2017-12-07

摘要: 目的:对新资源食品元宝枫种仁中的化学成分进行研究。方法:采用硅胶、聚酰胺、凝胶(Sephadex LH-20)柱色谱及重结晶等技术进行分离纯化,综合运用质谱和波谱学方法鉴定化合物结构。结果:从元宝枫种仁70%乙醇溶液提取物中分离鉴定了12 种化合物,分别为二氢去氢二愈创木基醇-4’-O-β-D-葡萄糖苷(1)、1,2,3,6-四没食子酰基-O-β-D-吡喃葡萄糖(2)、1,2,3,4,6-五没食子酰基-O-β-D-吡喃葡萄糖(3)、槲皮素(4)、山柰酚-3-O-α-L-吡喃鼠李糖苷(5)、槲皮素-3-O-α-L-吡喃鼠李糖苷(6)、槲皮素-3-O-β-D-吡喃半乳糖苷(7)、槲皮素-3-O-α-L-吡喃阿拉伯糖苷(8)、阿夫儿茶素(9)、儿茶素(10)、表儿茶素(11)、胡萝卜苷(12)。结论:经SciFinder检索发现,化合物1~12均为首次从元宝枫种仁中分离得到,其中化合物1、2、9~11为首次从槭树属植物中分离得到。

关键词: 元宝枫, 新资源食品, 化学成分

Abstract: Objective: To study the functional components from the kernel of Acer truncatum Bunge as a new food resource. Methods: The chemical constituents were isolated and purified by sequential chromatographies on silica gel, polyamide and Sephadex LH-20 columns and recrystallization. Electrospray ionization mass spectrometry (ESI-MS), 1H-NMR and 13C-NMR spectroscopic analysis were employed for the structural elucidation. Results: A total of twelve compounds were obtained and they were chemically identified as (7S,8R)-urolignoside (1), 1,2,3,6-tetra-O-galloyl-β-D-pyranglucose (2), 1,2,3,4,6-penta-O-galloyl-β-D-pyranglucose (3), quercetin (4), kaempferol-3-O-α-L-rhamnopyranoside (5), quercetin-3-O-α-L-rhamnopyranoside (6), quercetin-3-O-β-D-galactopyranoside (7), quercetin-3-O-α-L-arabinopyranoside (8), (+)-afzelechin (9), (+)-catechin (10), (-)-epicatechin (11), and daucosterol (12). Conclusions: All these compounds were identified for the first time in the kernel of this plant, while compounds 1, 2, and 9-11 were obtained for the first time from the genus Acer.

Key words: Acer truncatum, new food resource, chemical composition

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