食品科学 ›› 2009, Vol. 30 ›› Issue (7): 33-35.doi: 10.7506/spkx1002-6630-200907006

• 基础研究 • 上一篇    下一篇

老姜与鲜姜超临界提取物的化学成分分析

战琨友1,尹洪宗2,张显忠3,徐坤1   

  1. 1.作物生物学国家重点实验室,山东农业大学园艺科学与工程学院 2.山东农业大学化学与材料科学学院 3.泰山医学院生物科学系
  • 收稿日期:2008-06-27 修回日期:2008-09-03 出版日期:2009-04-01 发布日期:2010-12-29
  • 通讯作者: 徐坤 E-mail:xukun@sdau.edu.cn
  • 基金资助:

    农业部“948”项目(2006-G15)

Chemical Composition Analysis on SEF-CO2 Extracts of Seed Ginger and Fresh Ginger

ZHAN Kun-you1 YIN Hong-zong2 ZHANG Xian-zhong3 XU Kun1,*   

  1. (1.State Key Laboratory of Crop Biology, College of Horticulture Science and Engineering, Shandong Agricultural University, Tai an
    271018, China 2. College of Chemsitry and Material Science, Shandong Agricultural University, Tai an 271018, China
    3. Department of Biological Sciences, Taishan Medical University, Tai an 271016, China)
  • Received:2008-06-27 Revised:2008-09-03 Online:2009-04-01 Published:2010-12-29
  • Contact: XU Kun1,* E-mail:xukun@sdau.edu.cn

摘要:

为确定老姜和鲜姜的成分差异及功效,采用气相色谱-质谱联用技术鉴定了老姜和鲜姜超临界CO2提取物的化学成分及相对含量。结果表明,老姜及鲜姜姜油树脂的提取率分别为5.15%±0.12%和4.67%±0.15%,两者所含的化学成分基本相同,主要为α-姜烯、β-倍半水芹烯、β-没药烯、α-法尼烯、α-姜黄烯、6-姜酚、6-姜烯酚及分解物姜油酮等,但相对含量差异显著。在呈香性萜类化合物中,老姜中1,8-桉树脑、β-香芧醛、柠檬醛、香叶醇、乙酸香叶酯及α-姜烯等化合物的相对含量显著低于鲜姜,且γ-芹子烯和大香叶烯D仅在鲜姜中检测出,而老姜中α-姜黄烯的相对含量显著高于鲜姜。老姜中姜辣素类化合物总的相对含量比鲜姜高7.86%,特别是6-姜烯酚和10-姜烯酚的相对含量分别比鲜姜高15.49%和30.51%。

关键词: 老姜, 鲜姜, 化学成分, 气质联用

Abstract:

Chemical composition of supercritical CO2 extracts of seed ginger and fresh ginger were analyzed by using GC-MS. Results indicated that the oleoresin yields of seed ginger and fresh ginger are 5.15% ± 0.12% and 4.67% ± 0.15%,respectively. No differences exist on chemical compositions between the two extracts, which mainly contain α-zingiberene, β-sesquiphellandrene, β-bisobolene, α-farnesene, α-curcumene, 6-gingerol, 6-shogaol and zingerone. However, the contents of these compounds are different significantly. The seed ginger extract contains less terpenoids than the fresh ginger extract, namely 1,8-cineole, β-citronellal, citral, geraniol, geranyl acetate, α-zingiberene and the other two terpenoids of γ-selinene, germacrene D are only detected in fresh ginger extract. The relative content of α-curcumene in seed ginger extract is higher than that in fresh ginger extract. Seed ginger extract also possesses more gingerols than fresh ginger by 7.86%, especially 6-shogaol and 10-shogaol, whose relative contents are higher 15.49% and 30.51% than those in fresh ginger extract.

Key words: seed ginger, fresh ginger, chemical composition, GC-MS

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