食品科学 ›› 2008, Vol. 29 ›› Issue (10): 37-40.

• 基础研究 •    下一篇

山楂果胶中多聚半乳糖醛酸多糖的化学构造特征

 李拖平, 李苏红, 王娜, 郭梅   

  1. 天津农学院食品科学系; 筑波大学生命环境科学研究科;
  • 出版日期:2008-10-15 发布日期:2011-12-08

Structural Features of Polygalacturonan in Haw Pectin

 LI  Tuo-Ping, LI  Su-Hong, WANG  Na, GUO  Mei   

  1. 1.Department of Food Science,Tianjin Agricultural University,Tianjin 300384,China; 2.Faculty of Life and Environmental Sciences,University of Tsukuba,Tsukuba 305-8572,Japan
  • Online:2008-10-15 Published:2011-12-08

摘要: 山楂果胶中的酸性糖组分Hf2是一种多聚半乳糖醛酸多糖(polygalacturonan),其30%可被果胶裂解酶所分解。对Hf2的化学构造分析的结果表明,Hf2的1/3由α-(1→4)结合的α-D-半乳糖醛酸(galanturonicacid)构成,在半乳糖醛酸的C-2或C-3位上又具有由甘露糖及(或)半乳糖结合所构成的侧链。剩余的2/3中,由→4)-α-GalA(1→2)Rha(1→键合形成其构造的主链,而由(1→5)键合的阿拉伯聚糖(arabinan)以及4位被取代的半乳糖,4位被取代的甘露糖等糖残基结合于鼠李糖的C-4位上而构成其构造部分的侧链。

关键词: 山楂, 果胶, 化学构造, 多聚半乳糖醛酸多糖

Abstract: 30% Fraction Hf2 of how pectin that confers the property of high viscosity to haw pectin was digested by by pectolyase. Chemical structure analysis by GLC and MS showed that Hf2 is a polygalacturonan,in which about 1/3 of the main chain is composed of (1→4)-linked GalA,and 2/3 is composed of (1→2)-linked GalA and Rha. The analysis also suggested that (1→5)-linked Arabinan and 4-O-substituted galactose,4-O-substituted mannose etc. residues should be present as side chains in the moiety of Hf2 of haw pectin.

Key words: haw, pectin, chemical structure, polygalacturonan