食品科学 ›› 2009, Vol. 30 ›› Issue (7 ): 52-56.doi: 10.7506/spkx1002-6630-200907011

• 基础研究 • 上一篇    下一篇

肉类罐头食品中双酚A二缩水甘油醚及其衍生物的迁移

罗生亮1,吴少林1,张朝晖2,*,周光漪2,高洋洋2,李 晶2   

  1. 1.南昌航空大学环境与化学工程学院 2.北京出入境检验检疫局
  • 收稿日期:2009-02-10 出版日期:2009-04-01 发布日期:2010-12-29
  • 通讯作者: 张朝晖2,*, E-mail:zhaohui77cn@yahoo.com.cn
  • 基金资助:

    国家质检总局科技计划项目(2006IK119)

Migration of Bisphenol A Diglycidyl Ether and Its Derivatives into Canned Meat and Fish

LUO Sheng-liang1 WU Shao-lin1 ZHANG Zhao-hui2,* ZHOU Guang-yi2 GAO Yang-yang2 LI Jing2   

  1. (1.Institute of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China
    2. Beijing Entry-Exit Inspection and Quarantine Bureau, Beijing 100026, China)
  • Received:2009-02-10 Online:2009-04-01 Published:2010-12-29
  • Contact: ZHANG Zhao-hui2,* E-mail:zhaohui77cn@yahoo.com.cn

摘要:

本实验应用高效液相色谱-电喷雾串联质谱法分析检测肉类罐头食品中双酚A二缩水甘油醚(BADGE)及其衍生物的残留,重点研究了肉类罐头中的内容物、存储时间(6个月、9个月、12个月)以及存储温度(4、20、100℃)对双酚A二缩水甘油醚(BADGE)及其衍生物的迁移量的影响,单因素方差分析(One-way ANOVA)检验实验结果表明,不同内容物罐头中从内壁涂层迁移至样品的BADGE及其衍生物存在显著性差异(p<0.05),Student-Newman-Keuls法检验表明存储12个月后目标化合物的迁移量与6个月、9个月存在显著性差异,存储温度为4、20℃时化合物迁移量没有显著差异,但是罐头加热到100℃后目标化合物迁移量是最大的。

关键词: 迁移, 高效液相色谱-电喷雾串联质谱, 双酚A二缩水甘油醚及其衍生物, 肉类罐头

Abstract:

A comprehensive analytical method based on high liquid chromatography-electrospray ionization tandem mass spectrometry with positive ionization mode was applied for measuring bisphenol A diglycidyl ether (BADGE) and its derivatives in canned meat and fish. Effects of contents in cans, storage time (6, 9 or 12 months) and temperature (4 ℃, 20 ℃ or 100 ℃) on migration of BADGE and its derivatives from varnish to canned contents were investigated. One-way analysis of variance (ANOVA) showed that there are significant differences among different canned contents (p <0.05). Student-Newman-Keuls analysis indicated that levels of BADGE and its derivatives at 12 months are significantly higher than those at 6 and 9 months. There are no significant differences between 4 ℃and 20 ℃, but when the cans are heated to 100 ℃, the levels of BADGE and its derivatives migration is the highest.

Key words: migration, high performance liquid chromatography-ESI-tandem mass spectrometry, bisphenol A diglycidyl ether (BADGE) and its derivatives, canned meat and fish

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