食品科学 ›› 2014, Vol. 35 ›› Issue (6): 176-179.doi: 10.7506/spkx1002-6630-201406038

• 分析检测 • 上一篇    下一篇

天然姜油掺假的气相色谱-质谱定性鉴别

胡艳云1,2,徐慧群1,宋 伟1,2,吕亚宁1,2,王岚峰1,韩 芳1,2,郑 平1,2,*   

  1. 1.安徽出入境检验检疫局,安徽 合肥 230022;2.食品安全分析与检测安徽省重点实验室,安徽 合肥 230022
  • 收稿日期:2013-06-25 修回日期:2014-03-11 出版日期:2014-03-25 发布日期:2014-04-04
  • 通讯作者: 郑平 E-mail:ahciq_hx@163.com
  • 基金资助:

    炒货食品安全相关检测技术的研究

Identification of Adulterated Natural Ginger Oil Using Gas Chromatography-Mass Spectrometry

HU Yan-yun1,2, XU Hui-qun1, SONG Wei1,2, Lü Ya-ning1,2, WANG Lan-feng1, HAN Fang1,2, ZHENG Ping1,2,*   

  1. 1. Anhui Entry-Exit Inspection and Quarantine Bureau, Hefei 230022, China;
    2. Anhui Province Key Laboratory of Analysis and Detection for Food Safety, Hefei 230022, China
  • Received:2013-06-25 Revised:2014-03-11 Online:2014-03-25 Published:2014-04-04
  • Contact: ZHENG Ping E-mail:ahciq_hx@163.com

摘要:

采用气相色谱-质谱法,对姜油掺假植物性豆油进行鉴定分析。姜油经甲酯衍生化后,采用气相色谱-质谱
仪进行分析,检测姜油中是否含有豆油的特征成分(十八碳一烯酸、十八碳二烯酸、十八烷酸和十六烷酸),判断
姜油样品中是否掺杂豆油。结果表明:姜油经过甲酯衍生化后,利用豆油的特征性峰,能鉴别出姜油中是否掺有豆
油,检出限可达1%。该方法灵敏度较高、定性鉴别结果可靠,可以为姜油的质量安全控制提供重要的技术依据。

关键词: 姜油, 掺假, 豆油, 气相色谱-质谱

Abstract:

A rapid and sensitive method was proposed for the identification of ginger oil adulterated with soybean oil
using gas chromatography-mass spectrometry (GC-MS). The method was based on the identification of the characteristic
components including methyl palmitate, methyl linoleate, methyl oleate and methyl stearate in soybean oil by GC-MS after
ginger oil sample was derivatized by methyl ester. The necessity of derivatization with methyl ester was discussed, and the
GC-MS chromatograms for pure ginger oil and adulterated one were compared before and after methyl ester derivation. The
results showed that the minimum content of 1% soybean oil in ginger oil could be detected according to the characteristic
peaks of soybean oil. Being sensitive and reliable, the proposed method can provide an effective technique for the quality
control of ginger oil.

Key words: ginger oil, adulteration, soybean oil, gas chromatography-mass spectrometry (GC-MS)

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