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电子鼻结合化学计量法对羊奶中的蛋白质掺假的识别

贾茹,张娟,王佳奕,丁武   

  1. 陕西杨凌西北农林科技大学食品科学与工程学院
  • 收稿日期:2016-07-14 修回日期:2017-01-19 出版日期:2017-04-25 发布日期:2017-04-24
  • 通讯作者: 丁武 E-mail:dingwu10142000@163.com
  • 基金资助:
    原料奶中抗生素残留电子鼻快速检测技术研究;国家自然科学基金项目

Recognition of Goat Milk Adulterated with Proteins using Electronic Nose with Chemometric Methods

2, 2,   

  • Received:2016-07-14 Revised:2017-01-19 Online:2017-04-25 Published:2017-04-24

摘要: 利用电子鼻结合化学计量法对羊奶中的蛋白质掺假进行了定性和定量的研究。用电子鼻检测掺入了不同蛋白质物质的羊奶,采用主成分分析 (PCA)、线性判别分析 (LDA) 对电子鼻响应值进行定性分析,采用线性回归分析、Fisher判别分析 (FDA) 以及K-最邻近值分析 (KNN) 来对电子鼻响应值进行定量分析。结果表明:主成分分析和线性判别分析都能够区分不同类别的掺假样品。线性回归分析的决定系数为84.5%,表明回归方程估测可靠程度较高。Fisher判别分析的原始分类的正确率达到100.0%,交叉验证的正确率为98.2%,说明其预测结果较好。K-最邻近值分析对训练集的分类正确率达到95.1%,对验证集的分类正确率为97.1%,说明模型的预测结果良好。说明应用电子鼻技术检测羊奶中的蛋白质掺假具有一定的可行性。

关键词: 羊奶, 蛋白质掺假, 电子鼻, 化学计量法

Abstract: Goat milk adulterated with proteins was qualitatively discriminated and quantitatively analyzed using electronic nose combined with chemometric methods. Goat milk adulterated with proteins was detected by electronic nose and then the electronic nose response value was qualitative analyzed by principal component analysis (PCA), linear discriminant analysis (LDA), and the electronic nose response value was quantitative analyzed by linear regression analysis, Fisher discriminant analysis (FDA) and K nearest neighbor analysis (KNN). The results showed that: the principal component analysis and linear discriminant analysis are able to distinguish between different adulterations. The decision coefficient of linear regression analysis was 84.5%, which indicated that the reliability of the regression equation was high. The accuracy of the original classification of Fisher discriminant analysis reached 100%, and cross validation was 98.2%, indicating that the forecasting result is well. The classification accuracy of the training set of K nearest neighbor analysis is 95.1%, and the classification accuracy rate of the validation set is 97.1%, indicating that the prediction results of the model are well. All of these showed that electronic nose technology has certain feasibility in recognition of protein adulterations in goat milk.

Key words: goat milk, protein adulterations, electronic nose, chemometric methods

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