食品科学 ›› 2012, Vol. 33 ›› Issue (10): 131-135.doi: 10.7506/spkx1002-6630-201210027

• 工艺技术 • 上一篇    下一篇

莴笋叶渣吸附Cu2+研究

陈莉   

  1. 运城学院生命科学系
  • 出版日期:2012-05-25 发布日期:2012-05-07

Bio-adsorption of Copper Ions by Residue of Asparagus Lettuce Leaf

CHEN Li   

  1. (Department of Life Science, Yuncheng University, Yuncheng 044000, China)
  • Online:2012-05-25 Published:2012-05-07

摘要: 采用二次回归正交旋转组合设计方法对莴笋叶渣吸附Cu2+条件进行优化,建立加入量(X1)、质量浓度(X2)、时间(X3)、pH值(X4)、温度(X5)5个因素与吸附率(Y)的回归模型为:Y=85.45862+11.80098X1-6.85546X2+0.24918X3+2.14203X4+1.12124X5-4.75315X12-2.40953X22-2.23141X32-1.49228X42-3.40533X52+3.84570X1X2+0.61717X1X3-3.15888X1X4-0.26948X1X5-0.29760X2X3+0.77899X2X4-0.01867X2X5-0.23965X3X4-1.45840X3X5+0.94533X4X5。各因素对莴笋叶渣吸附Cu2+影响顺序为:加入量>质量浓度>pH值>温度>时间,在加入量0.9g、Cu2+质量浓度30mg/L、时间5h、pH3、温度40℃条件下,莴笋叶渣对Cu2+吸附率最高可达98.40%。验证值为97.96%,与理论值基本一致。对于60mg/L Pb2+溶液,莴笋叶渣为吸附剂时的最佳固液比为12g/L;莴笋叶渣对中低质量浓度Pb2+溶液的吸附效果好于活性炭。

关键词: 莴笋叶渣, 铜离子, 吸附, 优化, 二次回归正交旋转组合设计, 固液比

Abstract: Copper ion adsorption conditions by asparagus lettuce leaf residue were optimized through quadratic regression orthogonal design. A quadratic regression orthogonal model was established to express relationship between adsorption rate (Y) and five factors including addition amount (X1), concentration (X2), time (X3), pH (X4), and temperature (X5). The relationship was shown in the following equation: Y =85.45862+11.80098X1-6.85546X2+0.24918X3+2.14203X4+1.12124X5-4.75315X12-2.40953X22-2.23141X32-1.49228X42-3.40533X52+3.84570X1X2+0.61717X1X3-3.15888X1X4-0.26948X1X5-0.29760X2X3+0.77899X2X4-0.01867X2X5-0.23965X3X4-1.45840X3X5+0.94533X4X5. The factor order on Cu2+ adsorption rate from strong to weak was addition amount, concentration, pH, temperature and time. According to this model, conditions under 0.9 g addition amount of asparagus lettuce leaf residue in 30 mg/L for 5 h using pH 3 and 40 ℃ revealed the highest adsorption, which was 98.40%. The experiment result was consistent with the theoretical result of 97.96%. The best solid to liquid radio of Cu2+ adsorption by asparagus lettuce leaf residue is 12 g/L. In the low concentration of Cu2+ solution, the adsorption of asparagus lettuce leaf residue is better than activated carbon.

Key words: asparagus lettuce leaf residue, Cu2+, adsorption, optimization, quadratic regression orthogonal design, solid to liquid radio

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