Determination of Titanium Acetyl Acetone in Polyethylene Film’s Printing Layer and Its Stability

Abstract

Abstract: Gas chromatography mass spectrometry (GC-MS) and liquid chromatography mass spectrometry (LC-MS) methods for detecting acetylacetone were established and optimized, and the existence form of titanium acetyl acetone was identified using the proposed methods. The content of acetylacetone and titanium in titanium acetyl acetone, gloss oil, ink, and printed matter was detected using high-performance liquid chromatography (HPLC) and inductively coupled plasma optical emission spectrometer(ICP-OES), respectively. The ultraviolet-treated and heat-treated titanium acetyl acetone was studied using fourier infrared spectroscopy. Results indicated that acetylacetone and titanium exist in the form of ions in the titanium acetyl acetone standard solution, acetylacetone and titanium ions need to be detected separately. Titanium was detected in the samples of gloss oil, ink, titanium acetyl acetone and printing matter, acetylacetone was detected in gloss oil and titanium acetyl acetone but not in ink and printed matter. After heat and ultraviolet-treating of titanium acetyl acetone, oxidation reaction occurs in the carbon-carbon double bond, which means this substance has changed.

Key words: gas chromatography(GC), liquid chromatography (LC), mass spectrometry (MS), inductively coupled plasma optical emission spectrometer (ICP-OES), titanium acetyl acetone (TAA), printing inks

CLC Number:

Huaining Zhong. Determination of Titanium Acetyl Acetone in Polyethylene Film’s Printing Layer and Its Stability[J]. FOOD SCIENCE.

References

[1]高松.纸包装油墨中增塑剂的迁移研究[D]. 江南大学, 2014.
[2]许亚宁, 杜维维.食品包装印刷油墨中有害成分分析及检测方法[J].今日印刷, 2015, (12):63-66
[3]朱金红, 张欣涛.油墨中23种邻苯二甲酸酯含量的检测[J].印染, 2017, (9):44-46
[4]Kanngie?er B, Hahn O, Wilke M, et al.Investigation of oxidation and migration processes of inorganic compounds in ink-corroded manuscripts[J].Spectrochimica Acta Part B, 2004, 59(10):1511-1516
[5]Oesterreicher A, Roth M, Hennen D, et al.Low migration type I photoinitiators for biocompatible thiol-ene formulations[J].European Polymer Journal, 2017, 88::393-402
[6]Papilloud S, Baudraz D.Migration tests for substrates printed with UV ink systems in aqueous simulants[J].Progress in Organic Coatings, 2002, 45:231-237
[7]Clemente I, Aznar M, Nerin C, et al.Migration from printing inks in multilayer food packaging materials by GC-MS analysis and pattern recognition with chemometrics[J].Food Additives and Contaminants Part A, 2016, 33(4):703-714
[8]Luis Aparicio J, Elizalde M.Migration of Photoinitiators in Food Packaging: A Review[J].Packaging Technology and Science, 2015, 28(3):181-203
[9]Aznar M, Alfaro P, Nerin C, et al.Progress in mass spectrometry for the analysis of set-off phenomena in plastic food packaging materials[J].Journal of Chromatography A, 2016, 1453:124-133
[10]Aznar M, Dome?o C, Nerín C, et al.Set-off of non volatile compounds from printing inks in food packaging materials and the role of lacquers to avoid migration[J].Dyes and Pigments, 2015, 114:85-92
[11]Marszewski M, Marszewska J, Pylypenko S, et al.Synthesis of Porous Crystalline Doped Titania Photocatalysts Using Modified Precursor Strategy[J].Chemistry of Materials, 2016, 28(21):7878-7888
[12]刘青宝.乙酰丙酮金属化合物的合成及其对PVC的热稳定作用研究[D]. 北京化工大学, 2009.
[13]翟宇恺, 李轶.乙酰丙酮金属化反应研究[J].应用化工, 2013, 42(12):2249-2251
[14]Ballantyne B.Systemic toxicity from repeated cutaneous contact with 2,4-pentanedione[J].Veterinary and Human Toxicology, 2001, 43(1):14-18
[15]European Printing Ink Association. EuPIA Communication Paper on 2,4-Pentanedione. 6 January 2006
[16]Kissa E.Determination of acetylacetone and alcohols in titanium chelates[J].Analytica Chimica Acta, 1993, 281(2):385-389
[17]徐水平.乙酰丙酮混合物的气相色谱法测定[J].浙江化工, 1997, (4):44-45
[18]Zeng H, Duan Z, Chen H, et al.Determination of 2,6-Dimethyl-gamma-pyrone and Acetylacetone by High Performance Liquid Chromatography[J].Chinese Journal of Analytical Chemistry, 2011, 39(3):382-386
[19]Li G, Zheng D, Peng H, et al.Determination of Acetylacetone with HPLC[J].Chemical World, 2010, 7(2010):398-400
[20]曾红艳, 段正康, 陈韩志, 等.高效液相色谱法测定, -二甲基吡喃酮和乙酰丙酮的含量[J].分析化学, 2011, 39(3):382-386
[21]李广梅, 郑典模, 彭海龙, 等.高效液相色谱法测定乙酰丙酮含量[J].化学世界, 2010, 51(7):398-400
[22]曾红艳, 段正康, 罗爱文, 等.高效液相色谱法同时测定乙酰丙酮反应液中的乙酰丙酮和丙酮[J].色谱, 2010, 28(10):955-958
[23]Lin Q B, Song X C, Fang H, et al.Migration of styrene and ethylbenzene from virgin and recycled expanded polystyrene containers and discrimination of these two kinds of polystyrene by principal component analysis[J].Food Additives and Contaminants Part A, 2017, 34(1):126-132
[24]杨丽香, 盛颖晗, 尹德胜.高光水性上光油的研制及检测[J].福建分析测试, 2011, 20(4):44-47
[25]李霞.高光泽水性上光油的研究[D]. 西安理工大学, 2006.
[26]Lin Q B, Li H, Zhong H N, et al.Migration of Ti from nano-TiO?-polyethylene composite packaging into food simulants[J].Food Additives & Contaminants Part A, 2011, 31(7):1284-1290