食品科学 ›› 2013, Vol. 34 ›› Issue (2): 220-223.

• 分析检测 • 上一篇    下一篇

电化学分析法快速鉴别煎炸大豆油的食用品质

高向阳   

  1. 河南农业大学食品科学技术学院
  • 收稿日期:2011-12-28 修回日期:2012-11-29 出版日期:2013-01-25 发布日期:2013-01-15
  • 通讯作者: 高向阳 E-mail:ndgaoxy@163.com
  • 基金资助:

    河南省重点学科建设基金资助

Rapid Identification of Edible Quality for Fried Soybean Oil by Electrochemical Analysis

GAO xiang-yang   

  • Received:2011-12-28 Revised:2012-11-29 Online:2013-01-25 Published:2013-01-15
  • Contact: GAO xiang-yang E-mail:ndgaoxy@163.com

摘要:

摘 要:为寻找快速鉴别煎炸油食用品质特性的新型表述参数同时进行现场快速分析,以国家颁布的羰基价指标为对照标准,用不同产地的市售食用大豆油为样品,用间断性反复煎炸油条的方法,研究煎炸过程中,当羰基价的含量超出国家标准时,煎炸油pH值和电导率的变化规律。结果表明:随着煎炸时间的延长,大豆油的羰基价明显升高,pH值逐渐降低,电导率先上升后稍微下降;累计煎炸12h时,羰基价已超过国家标准,此时pH均值为4.16,H+活度、电导率为新鲜豆油的100倍和5倍左右,大豆油不宜再食用;羰基价、H+离子活度与煎炸时间,H+离子活度与羰基价之间均存在极显著的相关关系,电导率与煎炸时间、羰基价的相关程度一般显著。建议将pH值4.20作为快速鉴别煎炸大豆油食用品质特性的新型表述参数。

Abstract:

Abstract: In order to find the new parameters of edible quality for frying oil and to achieve rapid detection on the spot, the edible soybean oil from different areas were researched. Carbonyl value promulgated by the nation was taken as reference standard. The changes of pH value and conductivity were analyzed as carbonyl value exceeded the national standard during batch deep-frying. The results showed that the carbonyl value increased obviously, pH value decreased gradually, conductivity increased and then decreased slightly with the increase of frying time. After batch deep-frying 12h, soybean oil couldn't be used as food when carbonyl value had exceeded the national standard, pH value was 4.16, H+ activity was 100 times and conductivity was 5 times to the fresh soybean oil. There were obvious correlativity between carbonyl value, H+ activity and the frying time. The relationship between conductivity and the frying time, carbonyl value was significant generally. It suggested pH 4.20 was considered as a new expression parameter that could be used to identify the edible quality of fried soybean oil.

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