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• 基础研究 •    下一篇

油脂微波加热模型中3-MCPD脂肪酸酯的形成

周勇强1,聂少平2,李昌2,朱建鹏1   

  1. 1. 南昌大学
    2. 南昌大学食品科学与技术国家重点实验室
  • 收稿日期:2014-03-19 修回日期:2014-08-20 出版日期:2014-09-15 发布日期:2014-09-12
  • 通讯作者: 聂少平 E-mail:spnie@ncu.edu.cn
  • 基金资助:
    “十二五”国家科技支撑计划课题;国家重点基础研究发展计划(973计划)

Formation of Bound 3-chloropropane-1,2-diol in the Models Simulating Edible Oil Microwave Processing

  • Received:2014-03-19 Revised:2014-08-20 Online:2014-09-15 Published:2014-09-12
  • Contact: Shao-Ping NIE E-mail:spnie@ncu.edu.cn

摘要: 摘 要:通过建立油脂微波加热模型研究不同的油脂微波加热后3-氯-1,2丙二醇(3-chloropropane-1,2-diol,3-MCPD)脂肪酸酯含量的变化情况以及NaCl溶液、pH、时间、不连续微波和金属离子等因素对3-MCPD脂肪酸酯形成的影响。结果表明:(1)熟榨植物油微波加热后3-MCPD脂肪酸酯含量增加均超过9mg/kg,远超过其他植物油。(2)3-MCPD脂肪酸酯含量随NaCl溶液的浓度增加而增加,随NaCl溶液比例的增加呈先增加后减少趋势。(3)酸性环境促进3-MCPD脂肪酸酯形成,碱性环境则抑制。(4)微波加热10min内,3-MCPD脂肪酸酯含量与时间呈正相关。(5)微波总时间一定的情况下,不连续微波产生的3-MCPD脂肪酸酯明显少于连续微波。(6)金属离子作为催化剂参与活性中间物的形成,能明显地促进3-MCPD脂肪酸酯的形成。上述结果可为食品微波加工处理过程中危害物3-MCPD脂肪酸酯的控制研究提供数据支持。

关键词: 关键词:微波, 3-MCPD脂肪酸酯, NaCl, pH, 时间, 不连续微波, 金属离子

Abstract: Abstract:A series of experiments have been built and accomplished with certain models by simulating oil microwave processing in order to explore the formation of bound 3-chloropropane-1,2-diol (3-MCPD) which was closely related to different oil types, NaCl solution, pH, time, intermittent microwave processing and metal ions. The results are shown below, (1) Roasted oils had obvious increment of bound 3-MCPD after having been microwave processed, and the increment exceeded 9 mg/kg which was more than the increment of other oils. (2) The amount of 3-MCPD esters was increased with increasing concentration of sodium chloride solution and increased firstly and then decreased with increasing proportion of sodium chloride solution, reached maximum value at 20%. (3) Acidic condition can promote the formation of bound 3-MCPD, while alkaline condition will restrain the formation. (4) The amount of bound 3-MCPD increased with increasing time under 10 minutes. (5) When compared to continuous microwave processing for equal time, intermittent microwave processing would limit the production of bound 3-MCPD. (6) Metal ions could signally promote the formation of 3-MCPD esters as metal ions could act catalyst to promote the formation of reactive intermediates during the formation react of bound 3-MCPD.Therefore, this present study could be regarded as a data support for the research on limiting formation of 3-MCPD esters during microwave processing of foods.

Key words: Key words:microwave, bound 3-MCPD, NaCl, pH, time, intermittent microwave, metal ions

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