食品科学 ›› 0, Vol. ›› Issue (): 0-0.

• 食品化学 •    下一篇

再制干酪拉伸性的调控机制

沈建洋1,罗洁2   

  1. 1. 中国农业大学
    2. 湖南农业大学食品科学技术学院
  • 收稿日期:2022-07-27 修回日期:2023-04-24 出版日期:2023-08-25 发布日期:2023-09-01
  • 通讯作者: 罗洁 E-mail:luojie@hunau.edu.cn
  • 基金资助:
    湖南省自然科学青年基金项目

Study on the regulation mechanism of the stretchability of processed cheese

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  • Received:2022-07-27 Revised:2023-04-24 Online:2023-08-25 Published:2023-09-01

摘要: 再制干酪是以天然干酪为主要原料加工而成的干酪制品,具有质地均一、口感柔和、货架期长以及便于携带等优点,备受消费者青睐。拉伸特性是再制干酪产品重要的功能特性,其对产品的品质影响重大,然而目前市场上再制干酪的拉伸品质稳定性较差,关于再制干酪拉伸性的调控机理不清,限制了再制干酪的消费。本试验通过调控再制干酪体系乳化盐添加量(0.6%-3.0%)、pH值(5.4-5.8)和马铃薯醋酸酯淀粉添加量(0.125%-2%),研究再制干酪拉伸性的调控机制。研究结果显示,当乳化盐从0.6%增加至3.0%时,再制干酪中的结合钙含量从4.42 ± 0.05 g/kg降低至0.02 ± 0.04 g/kg,脂肪球粒径D[4, 3]从73.08 ± 3.16 μm降低至27.90 ± 2.55 μm,结合水含量从9.57 ± 0.25%增加至10.40 ± 0.25%,表明钙交联作用逐渐减弱,干酪的乳化效果增加,水合程度增加,从而导致拉伸性先升高后降低;当pH值从5.4增加至5.8时,再制干酪中的结合钙含量从2.01 ± 0.08 g/kg增加至2.74 ± 0.05 g/kg,脂肪球粒径D[4, 3]从36.36 ± 2.68 μm降低至21.37 ± 2.39 μm,傅里叶红外光谱显示O-H和N-H的弯曲振动吸收峰均向低波数移动,结合水含量从9.85 ± 0.16%增加至10.74±0.12%,表明钙交联作用、乳化效果和水合程度增加,从而导致拉伸性先升高后减低;当马铃薯醋酸酯淀粉从0.125%增加至2%时,脂肪球粒径D[4, 3]从54.17 ± 2.74 μm降低至29.92 ± 2.71 μm,结合水含量从9.90 ± 0.38%增加至11.00 ± 0.21%,表明干酪的乳化效果和水合程度增加,拉伸性先升高后降低,其中当马铃薯醋酸酯淀粉添加量达到2%时,淀粉与蛋白质出现相分离,拉伸性因而变差。综上,再制干酪的拉伸性受钙离子螯合程度、乳化效果、蛋白质分子间静电相互作用、水分分布以及蛋白质-多糖相行为等多方面的综合调控。

关键词: 再制干酪, 拉伸性, 钙分布, 水分分布, 乳化性

Abstract: Processed cheese is a type of cheese product processed with natural cheese as the main raw material,which has the advantages of uniform texture, soft taste, long shelf life and portability, and is favored by consumers. Stretchability is an important functional property of processed cheese products, which has a significant impact on the quality of products. However, at present, the regulation mechanism of the stretchability of processed cheese is not clear, which limits the consumption of processed cheese. In this experiment, the regulation mechanism of the stretchability of processed cheese was studied by regulating addition of emulsifying salt (0.6% - 3.0%), pH value (5.4-5.8) and addition of potato acetate starch (0.125% - 2%). The results showed that when the emulsifying salt increased from 0.6% to 3.0%, the content of bound calcium in processed cheese decreased from 4.42 ± 0.05 g/kg to 0.02 ± 0.04 g/kg, and the average fat globule size D[4, 3] decreased from 73.08 ± 3.16 μm to 27.90 ± 2.55 μm ,the bound water content increased from 9.57 ± 0.25% to 10.40 ± 0.25%, indicating that the calcium crosslinking effect gradually weakened, the emulsifying effect of cheese increased, and the hydration degree of cheese increased, resulting the stretchability increased first and then decreased.; When the pH value increased from 5.4 to 5.8, the content of bound calcium in processed cheese increased from 2.01 ± 0.08 g/kg to 2.74 ± 0.05 g/kg, and the average fat globule size D[4, 3] decreased from 36.36 ± 2.68 μm to 21.37 ± 2.39 μm. Fourier transform infrared spectroscopy showed that the bending vibration absorption peaks of O-H and N-H moved to low wavenumbers, and the bound water content increased from 9.85 ± 0.16% to 10.74 ± 0.12%, indicating that the calcium crosslinking effect, emulsifying effect and hydration degree increased, resulting the stretchability increased first and then decreased; When potato acetate starch increased from 0.125% to 2%, the average fat globule size D[4, 3] decreased from 54.17 ± 2.74 μm to 29.92 ± 2.71 μm. The bound water content increased from 9.90 ± 0.38% to 11.00 ± 0.21%, indicating that the emulsifying effect and hydration degree of cheese increased, and the stretchability increased first and then decreased. When the addition of potato acetate starch reached 2%, the starch and protein separated, and the stretchability became worse. In conclusion, the stretchability of processed cheese is comprehensively regulated by the degree of calcium ion chelation, emulsifying effect, electrostatic interaction between protein molecules, water distribution state and protein polysaccharide phase behavior

Key words: Processed cheese, stretchability, calcium distribution, moisture distribution, emulsibility

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