食品科学 ›› 2022, Vol. 43 ›› Issue (18): 76-82.doi: 10.7506/spkx1002-6630-20211028-309

• 食品化学 • 上一篇    

改性处理对大豆分离蛋白/壳聚糖/黑木耳多糖复合膜性质的影响

孙海涛,赵婉竹,赵兵兵,邵信儒,钟子杰,石金风,姜瑞平,刘鹏   

  1. (1.通化师范学院 长白山食用植物资源开发工程中心,吉林 通化 134000;2.通化师范学院食品科学与工程学院,吉林 通化 134000)
  • 发布日期:2022-09-28
  • 基金资助:
    吉林省科技发展计划项目(YDZJ202101ZYTS091);吉林省教育厅科学技术研究规划项目(JJKH20200485KJ); 大学生创新创业训练计划项目(202110201015;CS2020080)

Effect of Modification Treatment on the Properties of Soy Protein Isolate/Chitosan/Auricularia auricular Polysaccharide Composite Film

Sun Haitao, ZHAO Wanzhu, ZHAO Bingbing, Shao Xinru, ZHONG Zijie, SHI Jinfeng, JIANG Ruiping, LIU peng   

  1. (1. Changbai Mountain Edible Plant Resources Development Engineering Center, Tonghua Normal University, Tonghua 134000, China; 2. College of Food Science and Engineering, Tonghua Normal University, Tonghua 134000, China)
  • Published:2022-09-28

摘要: 利用超声波、微波、紫外光及其协同改性制备大豆分离蛋白、壳聚糖、黑木耳多糖复合膜,研究不同改性方法对膜性质影响。结果表明:超声波、微波、紫外光改性处理可改善膜的机械性能、阻隔性能,其中超声波微波协同改性作用最明显,膜的抗拉强度和断裂伸长率达到最大值(21.67 MPa和78.02%);水蒸气透过系数和氧气透过率达到最小值(1.34×10-12 g/(cm·s·Pa)、0.47×10-2 g/(m2·d))。超声波微波协同改性亦可显著增加膜的亮度和白度,提高膜的透光率。利用扫描电子显微镜、傅里叶变换红外光谱和热重分析对复合膜进行表征,表明经过超声波、微波、紫外光改性处理加强了膜分子间氢键作用,形成致密、稳定的网络结构,提高了复合膜热稳定性。

关键词: 超声波;微波;紫外光;协同改性处理;复合膜;大豆分离蛋白;壳聚糖;黑木耳多糖

Abstract: Chitosan-based composite film incorporated with soybean protein isolate and Auricularia auricular polysaccharide (SPI/CS/AAP) was modified by ultrasonic, microwave, ultraviolet (UV) or their combination to evaluate the effect of different modification methods on the film’s properties. The results showed that the mechanical properties and barrier properties of the film were improved by ultrasonic, microwave and UV modification treatments. Among them, the effect of ultrasonic-microwave synergistic modification was the most pronounced, resulting in the highest tensile strength (TS) and elongation at break (EAB) (21.67 MPa and 78.02%, respectively) and lowest water vapor permeability (WVP) and oxygen permeability (OP) (1.34 × 10-12 g/(cm·s·Pa) and 0.47 × 10-2 g/(m2·d), respectively). Furthermore, the synergistic modification could significantly increase the brightness, whiteness and light transmittance of the film. The composite film was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA), revealing that the hydrogen bonding between the film matrix molecules was strengthened by ultrasonic, microwave and UV treatments, and the modified film exhibited a dense and stable network structure and improved thermal stability.

Key words: ultrasonic; microwave; ultraviolet light; synergistic modification treatment; composite film; soy protein isolate; chitosan; Auricularia auricular polysaccharide

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