食品科学 ›› 2025, Vol. 46 ›› Issue (5): 48-56.doi: 10.7506/spkx1002-6630-20240430-282

• 基础研究 • 上一篇    下一篇

多维度解析渗透脱水传质:复配糖液和猕猴桃果块特性改变

李淑娟,王凤昭,毕金峰,吕健   

  1. (1.中国农业科学院农产品加工研究所,农业农村部农产品加工重点实验室,北京 100193;2.青岛农业大学食品科学与工程学院,山东 青岛 266109;3.山东省特种食品技术创新中心,山东 青岛 266109;4.青岛特种食品研究院,山东 青岛 266109)
  • 出版日期:2025-03-15 发布日期:2025-02-12
  • 基金资助:
    “十四五”国家重点研发计划项目(2022YFD1600704)

Multidimensional Characterization of Mass Transfer during Osmotic Dehydration: Changes in the Properties of Mixed Sugar Solutions and Dehydrated Kiwifruit Chunks

LI Shujuan, WANG Fengzhao, BI Jinfeng, LÜ Jian   

  1. (1. Key Laboratory of Agro-products Processing, Ministry of Agriculture and Rural Affairs, Institute of Food Science and Technology, Chinese Academy of Agricultural Sciences, Beijing 100193, China; 2. College of Food Science and Engineering, Qingdao Agricultural University, Qingdao 266109, China; 3. Shandong Technology Innovation Center of Special Food, Qingdao 266109, China; 4. Qingdao Special Food Research Institute, Qingdao 266109, China)
  • Online:2025-03-15 Published:2025-02-12

摘要: 本研究以蔗糖(sucrose,SUC)为基质,分别与低聚果糖(fructo-oligosaccharides,FOS)、低聚异麦芽糖(isomalto-oligosaccharides,IMO)和低聚木糖(xylo-oligosaccharides,XOS)形成复配糖液,以脉冲超声(pulsed-ultrasound,US)辅助渗透脱水技术制备以糖水为介质的猕猴桃果块。在系统解析复配糖液特性的基础上,追踪分析猕猴桃果块品质的形成规律,以多维度解析复配糖液介导的渗透脱水传质过程。结果表明,US辅助渗透脱水加速了传质过程,复配糖液的可溶性固形物(total soluble solid,TSS)含量、渗透压、电导率显著下降,浊度增加,其中US-SUC-XOS组呈现最大的TSS(23.65 °Brix)、渗透压(1 439.00 mOsm/L)、电导率(13 316.87 μS/cm)和浊度(12.50 NTU)。渗透脱水过程中,复配糖液的TSS和渗透压均降低,浊度增加,电导率呈先下降后升高的趋势,体现出渗透脱水过程中的传质作用。追踪分析猕猴桃果块品质变化发现,猕猴桃果块TSS含量持续增加,其中US-SUC-XOS-12 h组TSS含量最高(15.35 °Brix);糖分子进入细胞结构中,为细胞组织提供了支撑力,同时出现明显的质壁分离现象,诱导质构特性呈缓慢下降趋势;电学特性分析结果表明,渗透脱水加快了果块中带电粒子的运动,表现为果块阻抗值和电抗值降低,其中US-SUC-XOS组的黏附作用减缓了粒子运动,表现出最高的电阻值和电抗值;X射线能谱分析结果证实了元素间的传质,其中US-SUC-XOS-12 h组中K元素含量占比最多,为67.08%,Ca元素含量占比最少,为28.61%;核磁共振氢谱分析证实了复配糖液与猕猴桃果块中糖分子的传质;水分分布状态变化分析结果表明,复配糖分子渗入可诱导猕猴桃果块中大量自由水逸出,并降低水分子的移动性,其中US-SUC-XOS-12 h组自由水峰面积最低,不易流动水和结合水峰面积最高。综上,不同的复配糖液可介导不同程度传质的发生,其中SUC-XOS可减缓猕猴桃果块组织降解,有助于猕猴桃果块良好品质的形成。

关键词: 猕猴桃;复配糖液;渗透脱水;传质;电学特性

Abstract: In this study, using mixed solutions of sucrose (SUC) and fructo-oligosaccharides (FOS), isomalto-oligosaccharides (IMO), or xylo-oligosaccharides (XOS) as the medium, pulsed ultrasound (US)-assisted osmotic dehydration (OD) of kiwifruit chunks was carried out. Changes in the properties of mixed sugar solutions were systematically analyzed during the dehydration process, the quality formation of kiwifruit chunks was examined, and the process of mass transfer during OD was evaluated from a multidimensional perspective. Results showed that US accelerated the mass transfer. Specifically, the content of total soluble solids (TSS), osmotic pressure and conductivity of the mixed sugar solutions significantly decreased and the turbidity increased. US-SUC-XOS group showed the highest TSS content (23.65 °Brix), osmotic pressure (1 439.00 mOsm/L), conductivity (13 316.87 μS/cm) and turbidity (12.50 NTU). During the OD process, the TSS content and osmotic pressure of the mixed sugar solutions decreased, the turbidity increased, and the conductivity decreased first and then increased, indicating that mass transfer took place. Analysis of the quality changes of kiwifruit chunks demonstrated that the TSS content continued to increase. The highest TSS content (15.35 °Brix) was observed in the 12 h US-SUC-XOS group. Additionally, the infiltration of sugars could support cells, resulting in obvious plasmolysis, which in turn contributed to decreased texture properties. Analysis of electrical characteristics demonstrated that US-assisted OD facilitated the movement of charged particles, which was reflected in a decrease in the impedance and reactance values of kiwifruit chunks. Notably, in the US-SUC-XOS group, the adhesion effect slowed down the particle movement, leading to the highest impedance and reactance values. X-ray spectroscopy analysis confirmed the mass transfer of elements. The highest proportion of K (67.08%) and the lowest proportion of Ca (28.61%) were obtained in the 12 h US-SUC-XOS group. Additionally, 1H nuclear magnetic resonance (NMR) spectroscopy confirmed the mass transfer of sugar molecules between the mixed sugar solution and kiwifruit chunks. The moisture distribution results highlighted that the infiltration of sugar molecules could induce a large amount of free water to escape from kiwifruit chunks and reduce the mobility of water molecules. The 12 h US-SUC-XOS group showed the lowest peak area of free water and the highest peak area of immobile water and bound water. In summary, different mixed sugar solutions mediate different degrees of mass transfer. In particular, SUC-XOS solution can retard the degradation of kiwifruit tissues, in turn contributing to the formation of good quality in kiwifruit chunks.

Key words: kiwifruit; mixed sugar solutions; osmotic dehydration; mass transfer; electrical characteristics

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