食品科学 ›› 2025, Vol. 46 ›› Issue (24): 98-105.doi: 10.7506/spkx1002-6630-20250626-190

• 基础研究 • 上一篇    

添加辛烯基琥珀酸淀粉酯对鱼汤挥发性物质释放行为的影响及机制

张钰,胡逸凡,赵一鸣,周晨光,包玉龙   

  1. (江苏大学食品与生物工程学院,江苏 镇江 212013)
  • 发布日期:2025-12-26
  • 基金资助:
    江苏大学高级人才科研启动基金项目(20JDG062)

Effect and Mechanism of the Addition of Octenyl Succinic Anhydride-Modified Starch on the Release of Volatile Compounds from Fish Soup

ZHANG Yu, HU Yifan, ZHAO Yiming, ZHOU Chenguang, BAO Yulong   

  1. (School of Food and Biological Engineering, Jiangsu University, Zhenjiang 212013, China)
  • Published:2025-12-26

摘要: 本研究选取黑鱼鱼汤为研究对象,探究添加由辛烯基琥珀酸酐(octenyl succinate anhydride,OSA)与天然淀粉发生酯化反应得到的淀粉(OSA淀粉)(0、0.5、1.0、1.5、2.0 g/100 mL)对黑鱼汤乳液特性及挥发性风味物质的影响。结果表明,随着OSA淀粉添加量的增加,鱼汤乳液油滴变小且分布更均匀,激光扫描共聚焦显微镜观察结果显示,鱼汤中油滴平均粒径从未添加OSA淀粉组的5.98 μm降低至4.24 μm(2.0 g/100 mL OSA淀粉组)。OSA淀粉添加导致蛋白质在油-水界面的吸附量减少,乳液的Zeta电位绝对值逐渐减小,而乳液的接触角增大。鱼汤的电子鼻分析结果显示,随着淀粉添加量的增加,分别对芳香成分和醇类物质敏感的W1C、W2S传感器响应值呈先上升后下降趋势,在OSA淀粉质量浓度为1.0 g/100 mL时达到最大,随后又有所减小。利用气相色谱-质谱技术进一步分析鱼汤挥发性物质,OSA淀粉添加组中的壬醛、(E)-2-庚烯醛和(E)-2-辛烯醛含量都明显高于未添加OSA淀粉组,1-辛烯-3-醇含量普遍高于未添加OSA淀粉组。综上,OSA淀粉添加量的增加使鱼汤乳液油滴粒径逐渐减小,促进了鱼汤中风味物质的释放。

关键词: 鱼汤;乳液;辛烯基琥珀酸淀粉酯;挥发性物质

Abstract: This study investigated the effects of octenyl succinic anhydride-modified starch (OSA starch) at different concentrations (0, 0.5, 1.0, 1.5, and 2.0 g/100 mL) on the emulsion properties and volatile flavor compounds of snakehead fish soup. The results showed that the oil droplets in the fish soup became smaller and more uniformly distributed as the addition level of OSA starch increased. Confocal laser scanning microscopy (CLSM) revealed that the average diameter of oil droplets decreased from 5.98 μm in the control group to 4.24 μm at an OSA starch concentration of 2.0 g/100 mL. The addition of OSA starch reduced the adsorption of proteins at the oil-water interface, leading to a gradual decrease in the absolute value of the emulsion’s zeta potential, while the contact angle of the emulsion increased. Electronic nose (E-nose) analysis indicated that the response values of sensors W1C and W2S, which are sensitive to aromatic compounds and alcohols, respectively, increased with higher OSA starch concentration, peaking at 1.0 g/100 mL before declining. Gas chromatography-mass spectrometry (GC-MS) analysis revealed that the relative contents of volatile compounds such as nonanal, (E)-2-heptenal, and trans-2-octenal were significantly higher in the OSA starch-treated groups than those in the control group, while the content of 1-octen-3-ol generally elevated. In conclusion, increasing the OSA starch concentration progressively reduced the oil droplet size in the fish soup emulsion, thereby promoting the release of volatile flavor compounds.

Key words: fish soup; emulsion; octenyl succinate anhydride-modified starch; volatile compounds

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