FOOD SCIENCE ›› 2006, Vol. 27 ›› Issue (2): 42-45.
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HE Yi, SUN Ting
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Abstract: The inclusion complex of β-CD and 1-MCP was subjected to programmed heating process and weight-temperature data were recorded by thermogravimetric analyzer. Probable decomposition kinetics parameters were suggested by means of Satava-Sestak method, Ozawa method and Kissinger method as well. And kinetics parameters were obtained, too. The experi- mental result showed that the decomposition kinetics model forβ-CD and 1-MCP was stochasticly becoming stone with succedent growth, while the activating energy was 102.14kJ/mol, with pre-exponential factor as 3.63×1010. The kinetic equation of thermal decomposition is expressed as: dα/dT = [(A / φ)exp(- E / RT)]·[3(1-α)[- ln (1-α)]1/3/ 2.
Key words: 1-methylcyclopropene; &beta, -cyclodextrin; mechanism of the thermal decomposition reaction; thermogravimetry; non-isothermal kinetics;
HE Yi, SUN Ting. 1-甲基环丙烯; β-环糊精; 热分解反应机理; 热重法; 非等温动力学;[J]. FOOD SCIENCE, 2006, 27(2): 42-45.
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