食品科学 ›› 2010, Vol. 31 ›› Issue (2): 102-105.doi: 10.7506/spkx1002-6630-201002024

• 工艺技术 • 上一篇    下一篇

纳米ZnO/LDPE抗菌食品包装材料研制

高艳玲1,姜国伟2,张少辉1   

  1. 1.上海交通大学农业与生物学院 2.中国科学院应用化学研究所
  • 收稿日期:2009-01-13 修回日期:2009-08-28 出版日期:2010-01-15 发布日期:2010-12-29
  • 通讯作者: 高艳玲 E-mail:yygao@sjtu.edu.cn; gaoyanling_0808@163.com

Preparation of A Nano-structural ZnO/LDPE Antimicrobial Food Packaging Material

GAO Yan-ling1,JIANG Guo-wei2,ZHANG Shao-hui1   

  1. (1. School of Agriculture and Biology, Shanghai Jiao Tong University, Shanghai 200240, China;
    2. Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China)
  • Received:2009-01-13 Revised:2009-08-28 Online:2010-01-15 Published:2010-12-29
  • Contact: GAO Yan-ling1, E-mail:yygao@sjtu.edu.cn; gaoyanling_0808@163.com

摘要:

以低密度聚乙烯作为食品包装的基材,将活化处理的纳米级ZnO 通过融熔共混的方法添加到基材中,再将所得的粒料经过单螺杆挤出机及吹膜机吹塑成薄膜,即制得抗菌型纳米改性聚烯烃复合材料。以大肠杆菌、枯草芽孢杆菌、金黄色葡萄球菌、鼠伤寒沙门氏菌、单核增多性李氏杆菌、铜绿假单胞菌6 种食品中常见的污染菌作为测试菌株,在3 种不同条件下对其抗菌性能进行测试。结果表明:该材料对其中的4 种细菌具有明显的抗菌作用,在自然光、室温下材料的抗菌能力较强;在6 种细菌中对枯草芽孢杆菌的抗菌作用最强,其抗菌率在室温且有自然光照射的条件下达到最高值99.99%,在37℃、无光照的条件下最低为95.01%。

关键词: 纳米氧化锌, 抗菌, 食品包装, 低密度聚乙烯

Abstract:

A nano-structural ZnO/LDPE antimicrobial food packaging material was developed through the following steps: in the first step, activated nano-structural ZnO was dispersed into low density polyethylene (LDPE), a matrix material, by dissolving-melting-blending technique; in the second step, the resulted particulate polymer composite was blown into film by sequential treatment with a single screw extruder followed by a plastic film blowing machine; and finally the target product was obtained. Six species of common food-contaminating bacteria including Escherichia coliform, Bacillus subtilis, Staphylococcus aureus, Salmonella aertrycke, Listeria monocytogenes and Pseudomonas aeruginosa were used for testing the antimicrobial capability of the material under different illumination conditions: energy-saving lamp light (5 W, (37 ± 1) ℃), darkness (37 ± 1) ℃ and sunlight (20 ± 1) ℃. Results showed that the material had a significant antimicrobial activity against four of the 6 species of food-contaminating bacteria, which was stronger under sunlight than under other illumination conditions. Of all the tested bacterial species, the strongest inhibitory effect against Bacillus subtilis was observed, with a maximum inhibitory rate as high as 99.99% under sunlight illumination and a minimum value of 95.01% in darkness.

Key words: nano-structural ZnO, antimicrobial activitylfood packaginglLDPE

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