食品科学 ›› 2021, Vol. 42 ›› Issue (10): 255-261.doi: 10.7506/spkx1002-6630-20200428-361

• 成分分析 • 上一篇    下一篇

铁观音乌龙茶和红茶的香气化学特征分析

郭丽,杜正花,姚丽鸿,陈小兵,张弋,林智,郭雅玲,陈明杰   

  1. (1.福建农林大学园艺学院,福建 福州 350002;2.中国农业科学院茶叶研究所,浙江 杭州 310008)
  • 出版日期:2021-05-25 发布日期:2021-06-02
  • 基金资助:
    福建农林大学科技创新基金项目(CXZX2017350);国家现代农业(茶叶)产业技术体系建设专项(CARS-19); 中国农业科学院科技创新工程项目(CAAS-ASTIP-2014-TRICAAS)

Chemical Characterization of the Aroma of Tieguanyin Oolong Tea and Black Tea

GUO Li, DU Zhenghua, YAO Lihong, CHEN Xiaobing, ZHANG Yi, LIN Zhi, GUO Yaling, CHEN Mingjie   

  1. (1. College of Horticulture, Fujian Agriculture and Forestry University, Fuzhou 350002, China;2. Tea Research Institute, Chinese Academy of Agricultural Sciences, Hangzhou 310008, China)
  • Online:2021-05-25 Published:2021-06-02

摘要: 以铁观音茶鲜叶为材料,采用不同工艺加工成乌龙茶、红茶和绿茶,运用感官审评法评定茶样的香气品质,利用溶剂辅助风味蒸发-气相色谱-质谱/火焰离子化检测器法分析茶样中挥发性成分,研究铁观音茶香气品质及其主要挥发性组分的工艺差异。结果表明,不同工艺铁观音茶样的香气品质得分均高于90 分且呈现花香特征。铁观音茶中检测到52 种挥发性成分,其中芳樟醇类和脂肪酸酯类化合物是挥发性组分的主体。铁观音茶香气的品种特征组分有氧化芳樟醇II、氧化芳樟醇IV、芳樟醇、反-橙花叔醇、己酸-3-己烯酯、己酸-2-己烯酯、苯甲酸-3-己烯酯、苯甲酸己酯和新植二烯等。红茶工艺能促进芳樟醇及其氧化物、3-甲基丁酸-2-己烯酯、己酸-3-己烯酯、己酸-2-己烯酯、新植二烯、二氢猕猴桃内酯、β-紫罗酮和水杨酸甲酯等的形成,而乌龙茶工艺有利于脱氢芳樟醇、2,6-二甲基-3,7-辛二烯-2,6-二醇、反-橙花叔醇、辛酸-顺-3-己烯酯和苯甲酸己酯等的形成。综上所述,铁观音茶的香气化学特征与品种特有组分、加工工艺调控密切相关,可为铁观音新产品研发提供重要技术参考。

关键词: 铁观音;红茶;乌龙茶;加工工艺;香气;溶剂辅助风味蒸发;气相色谱-质谱/火焰离子化检测器

Abstract: In this study, the aroma quality of oolong tea, black tea and green tea manufactured from the fresh leaves of Camellia sinensis cv. Tieguanyin was determined by sensory evaluation, and their volatile compounds were determined by solvent-assisted flavor evaporation combined with gas chromatography-mass spectrometry/flame ionization detector. We found that all the Tieguanyin tea samples scored 90 points for aroma with a flowery note. In total, 52 volatile components were detected in the tea samples, with linalool and fatty acid esters being the major ones. The characteristic aroma components of Tieguanyin tea included oxidized linaool II, oxidized linaool IV, linalool, trans-nerolidol, hexanoic acid 3-hexenyl ester, hexanoic acid 2-hexenyl ester, benzoate 3-hexen-1-ol, benzoic acid hexyl ester and neophytadiene. Black tea processing could promote the formation of linalool and its oxides, butanoic acid 3-methyl-, 2-hexenyl ester, hexanoic acid 3-hexenyl ester, hexanoic acid 2-hexenyl ester, neophytadiene, dihydroactinidiolide, beta-ionone, methyl salicylate. Oolong tea processing was conducive to the formation of hotrienol, 2,6-dimethyl-3,7-octadiene-2,6-diol, trans-nerolidol, octanoic acid 3-hexenyl ester, and benzoic acid hexyl ester. In conclusion, the aroma characteristics of Tieguanyin tea were closely related to its species-specific components and the manufacturing technology used; which will provide an important technical reference for the development of new Tieguanyin tea.

Key words: Tieguanyin tea; black tea; oolong tea; manufacturing technology; aroma; solvent-assisted flavor evaporation; gas chromatography-mass spectrometry/flame ionization detector

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