超声波提取-原子吸收光谱法测定谷物中镉、铜、铅和锌的含量

doi:10.7506/spkx1002-6630-201308035

食品科学 ›› 2013, Vol. 34 ›› Issue (8): 168-171.doi: 10.7506/spkx1002-6630-201308035

超声波提取-原子吸收光谱法测定谷物中镉、铜、铅和锌的含量

顾佳丽，赵刚，马占玲

渤海大学化学化工与食品安全学院，辽宁锦州 121013

收稿日期:2011-12-19 修回日期:2013-03-08 出版日期:2013-04-25 发布日期:2013-05-07
通讯作者: 顾佳丽 E-mail:gujiali@yahoo.cn
基金资助:
国家自然科学基金项目;辽宁省自然科学基金;辽宁省教育厅重点实验室项目

Determination of Cadmium, Copper, Lead and Zinc in Grains by Ultrasound-Assisted Extraction Followed by Atomic Absorption Spectrometry

GU Jia-li，ZHAO Gang，MA Zhan-ling

College of Chemistry, Chemical Engineering and Food Safety, Bohai University, Jinzhou 121013, China

Received:2011-12-19 Revised:2013-03-08 Online:2013-04-25 Published:2013-05-07

摘要/Abstract

摘要： 优化超声波辅助提取-原子吸收光谱法测定大米等谷物中Cd、Cu、Pb和Zn含量的方法。结果表明：0.1g谷物(粒径＜50μm)中加入5mL HNO3 -H2O2溶液(2:1，v/v)，先预超声10min，再放入60℃超声水浴中超声提取10min后，Cd、Cu、Pb和Zn均可以被定量回收，加标回收率在96.0%～107.5%之间。t检验结果表明超声提取法与常规湿式消解法分析结果差异不显著。方法的相对标准偏差(RSD)为4.9%～7.0%，检出限为0.007～0.019mg/L。

关键词: 超声提取法, 金属元素, 谷物

Abstract: Determining of cadmium, copper, lead and zinc in grain using ultrasound-assisted extraction- atomic absorption spectrometry was optimized. The results indicated that 0.1 g of grain samples were treated with 5 mL of HNO3-H2O2 (2:1, V/V) followed by 10-min presonication and then transferred to ultrasound water bath (60 ℃) for 10 min. Cd, Cu, Pb, and Zn can be quantitatively recovered and the spiked recoveries ranged within 96.0%–107.5%. The results of t-test indicated that difference in the results from ultrasound-assisted extraction and conventional wet acid digestion was not significant. The relative standard deviations (RSD) were 4.9%–7.0%, the limits of detection were 0.007–0.019 mg/L.

Key words: ultrasound-assisted extraction, metallic elements, grain

中图分类号:

O611.5

顾佳丽，赵刚，马占玲. 超声波提取-原子吸收光谱法测定谷物中镉、铜、铅和锌的含量[J]. 食品科学, 2013, 34(8): 168-171.

GU Jia-li，ZHAO Gang，MA Zhan-ling. Determination of Cadmium, Copper, Lead and Zinc in Grains by Ultrasound-Assisted Extraction Followed by Atomic Absorption Spectrometry[J]. FOOD SCIENCE, 2013, 34(8): 168-171.

参考文献

[1] MUSTAFA T. Toxic and essential trace elemental contents in ?sh species from the Black Sea, Turkey[J]. Food and Chemical Toxicology, 2009, 47: 1785-1790.
[2] KAZI T.G, JAMALI M.K, ARAIN M.B, et al. Evaluation of an ultrasonic acid digestion procedure for total heavy metals determination in environmental and biological samples[J]. Journal of Hazardous Materials, 2009, 161: 1391-1398.
[3] 郭孝武, 冯岳松. 超声提取分离[M]. 北京：化学工业出版社, 2008: 11-13.
[4] 李辉,卜晓英, 陈功锡, 等. 超声辅助提取白背三七总黄酮[J]. 食品科学, 2011, 32(14): 144-146.
[5] GüNGOR H, ELIK A. Comparison of ultrasound-assisted leaching with conventional and acid bomb digestion for determination of metals in sediment samples[J]. Microchemical Journal, 2007, 86: 65-70.
[6] AFRIDI H. I., KAZI T. G., ARAIN M. B. Determination of cadmium and lead in biological samples by three ultrasonic-based samples treatment procedures followed by electrothermal atomic absorption spectrometry[J]. Journal of AOAC International, 2007, 90(2): 470-478.
[7] 刘长江, 王菲, 栾云峰等. 软枣猕猴桃黄酮超声辅助提取条件优化[J]. 食品科学, 2011, 32(14): 100-102.
[8] 杨敏, 杨树科, 王炯等.离子色谱法测定白菜中的硝酸盐、亚硝酸盐、磷酸盐及总磷、总氮[J]. 食品科学, 2010, 31(18): 216-219.
[9] FILGUEIRAS. A.V, CAPELO. J.L, LAVILLA. I, et al. Comparison of ultrasound-assisted extraction and microwave-assisted digestion for determination of magnesium, manganese and zinc in plant samples by flame atomic absorption spectrometry[J]. Talanta, 2000, 53: 433-441.
[10] TASNEEM G. K, HASSAN I. A, MOHAMMAD K. J, et al. Effect of ultrasound agitation on the release of heavy elements in certified reference material of human Hair (CRM BCR 397) [J]. Journal of AOAC International, 2006, 89(5): 1410-1416.
[11] 蔡艳荣, 刘媛, 李玲玲. 原子吸收光谱法测定水果中10 种元素含量及分布[J]. 卫生研究, 2011, 40(3): 361-364.
[12] CAPELO J.L, MADURO C, VILHENA C. Discussion of parameters associated with the ultrasonic solid–liquid extraction for elemental analysis (total content) by electrothermal atomic absorption spectrometry [J]. Ultrasonics Sonochemistry, 2005, 12: 225–232.
[13] GB2762-2005 食品中污染物限量[S]. 北京: 中国标准出版社，2005.
[14] NY861-2004 粮食中八种元素限量[S]. 北京: 中国标准出版社，2004.
[15] JúNIORA D. S, KRUGA F. J, PEREIRA M. G. Currents on ultrasound-assisted extraction for sample preparation and spectroscopic analytes determination[J]. Applied Spectroscopy Reviews, 2006, 41: 305–321.

超声波提取-原子吸收光谱法测定谷物中镉、铜、铅和锌的含量

Determination of Cadmium, Copper, Lead and Zinc in Grains by Ultrasound-Assisted Extraction Followed by Atomic Absorption Spectrometry

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