食品科学 ›› 2022, Vol. 43 ›› Issue (24): 210-222.doi: 10.7506/spkx1002-6630-20220302-023

• 成分分析 • 上一篇    

咖啡豆烘焙过程中油脂脂肪酸组成、挥发性风味及活性成分的演变规律

董聪慧,董文江,程金焕,胡荣锁,何红艳,陈小爱,龙宇宙,黄家雄,陈罡,陈舰飞   

  1. (1.宁夏大学食品与葡萄酒学院,宁夏 银川 750021;2.中国热带农业科学院香料饮料研究所,海南 万宁 571533;3.海南省特色热带作物适宜性加工与品质控制重点实验室,海南 万宁 571533;4.云南省农业科学院热带亚热带经济作物研究所,云南 保山 678600;5.普洱富民农业装备有限公司,云南 普洱 665000)
  • 发布日期:2022-12-28
  • 基金资助:
    “十三五”国家重点研发计划重点专项(2020YFD10012);海南省重点研发计划项目(ZDYF2021XDNY147); 中央级公益性科研院所基本科研业务费专项(1630142022010)

Evolution of Fatty Acid Composition, Volatile Flavors and Bioactive Ingredients of Coffee Oil during Coffee Bean Roasting

DONG Conghui, DONG Wenjiang, CHENG Jinhuan, HU Rongsuo, HE Hongyan, CHEN Xiao’ai, LONG Yuzhou, HUANG Jiaxiong, CHEN Gang, CHEN Jianfei   

  1. (1. School of Food and Wine Science, Ningxia University, Yinchuan 750021, China;2. Spice and Beverage Research Institute, Chinese Academy of Tropical Agricultural Sciences, Wanning 571533, China; 3. National Center of Important Tropical Crops Engineering and Technology Research, Wanning 571533, China; 4. Institute of Tropical and Subtropical Cash Crops, Yunnan Academy of Agricultural Sciences, Baoshan 678600, China; 5. Pu’er Fumin Agricultural Equipment Co. Ltd., Pu’er 665000, China)
  • Published:2022-12-28

摘要: 以云南小粒种咖啡豆为试材,系统研究烘焙过程中咖啡油脂理化性质、脂肪酸组成、挥发性成分及活性成分的变化规律。结果表明:随着烘焙度加深,油脂色泽加深;酸价呈增加的趋势,由1.60 mg/g增至3.75 mg/g;碘值反之,由142.04 g/100 g降至83.12 mg/100 g;茴香胺值先增大后减少,其值在3.40~16.26之间;皂化值略有降低,但无显著差异;共鉴定出11 种脂肪酸,主要为亚油酸相对含量在43.06%~64.39%之间,其次为硬脂酸和棕榈酸相对含量在12.67%~27.55%之间,油酸相对含量为9.03%~17.20%;脂肪酸组成影响不明显,但各脂肪酸的含量存在一定差异;利用气相色谱-质谱从极浅度到法式重度的咖啡油脂样品中分别检出25、33、36、53、54、59、64 种和58 种挥发性成分,主要成分有呋喃类化合物、吡嗪类化合物、酮类化合物、吡咯类化合物等,其种类和含量均呈减小趋势;活性成分中咖啡豆醇、α-生育酚、γ-生育酚、δ-生育酚含量均减少;而总酚含量不断增加,由7.75 mg/100 g升至15.96 mg/100 g。本研究结果可为咖啡精深加工及资源高值化利用提供理论依据和技术支撑。

关键词: 烘焙咖啡油脂;挥发性成分;脂肪酸组成;活性成分

Abstract: In this study, the physicochemical properties, fatty acid composition, volatile components and bioactive ingredients of oil from Arabica coffee beans from Yunnan roasted for different periods were systematically investigated. The results showed that as the degree of roasting increased, the color of the oil deepened, the acid value showed an increasing trend from 1.60 to 3.75 mg/g, the iodine value decreased from 142.04 to 83.12 mg/100 g, the anisidine value first increased and then decreased, ranging from 3.40 to 16.26, and the saponification value decreased slightly but not significantly. A total of 11 fatty acids were identified, the most predominant being linoleic acid, whose content ranged from 43.06% to 64.39%, followed by stearic and palmitic acids with contents ranging from 12.67% to 27.55% and oleic acid in the range of 9.03% to 17.20%. The effect of roasting degree on the type of fatty acid was not significant, but there were some differences in the content of fatty acid. A total of 25, 33, 36, 53, 54, 59, 64 and 58 volatile components were identified in oils from coffee beans roasted to eight different degrees from JQ to FZ, respectively. The major volatile components were furans, pyrazines, ketones and pyrroles, whose type and content showed a decreasing trend. The contents of bioactive ingredients including kahweol, α-tocopherol, γ-tocopherol and δ-tocopherol decreased, while the total phenolic content increased continuously from 7.75 to 15.96 mg/100 g. The results of this study provide a theoretical basis and technical support for the fine and deep processing and high-value utilization of coffee beans.

Key words: roasted coffee oil; volatile compound; fatty acid composition; bioactive components

中图分类号: