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• 分析检测 •    下一篇

傅立叶变换近红外光谱技术测定绿茶全氮量

杨丹,刘新,张颖彬,尹鹏   

  1. 中国农业科学院茶叶研究所
  • 收稿日期:2013-06-09 修回日期:2014-04-01 出版日期:2014-04-25 发布日期:2014-05-13
  • 通讯作者: 刘新 E-mail:liuxin@mail.tricaas.com
  • 基金资助:
    国家茶叶产业技术体系

Total nitrogen Determination in Green Tea by Fourier Transform Near Infrared Spectroscopy

2, 2   

  • Received:2013-06-09 Revised:2014-04-01 Online:2014-04-25 Published:2014-05-13

摘要: 建立了绿茶全氮量的偏最小二乘定量分析模型。在4691~3959、5126~4848cm-1波段区间内,光谱经过一阶导数与平滑处理后,模型的预测性能最好,外部验证集样品的预测值与化学测定值的预测均方差(RMSEP)为0.0925%,相关系数为0.9939。根据嫩度等级,建立了绿茶全氮量子模型,提高了模型的预测性能。嫩度为3级的子模型预测结果最好,验证集样品的全氮量的预测值与化学测定值的RMSEP值最小,为0.0379,相关系数为0.9961。绿茶全氮量近红外光谱检测技术是一种绿色、快速、高效的新型分析技术,能够实现快速测定绿茶全氮量,评价绿茶品质。试验对于丰富我国茶叶品质的快速检测手段,提高我国茶叶检测水平,都具有重要的学术意义和现实意义。

关键词: 近红外光谱技术, 绿茶, 全氮量, 子模型

Abstract: A calibration model of total nitrogen content in the green tea was established based on partial least square. The model demonstrated great predictive performance after the first derivative processing and smoothing, in spectrum range of 4691~3959 cm-1and 5126~4848cm-1. The correlation coefficient of predicted and chemical measurement value about the validation set was 0.9939 and the RMSEP was 0.0925%.Sub models of total nitrogen in green tea were established according to different tenderness. With the sub models, the prediction performance was improved. The prediction performance of the tenderness 3model was the best. The RMSEP and R about predicted and chemical measurement value were 0.0379% and 0.9961. The total nitrogen detection in green tea by Near Infrared Spectroscopy can achieve fast and efficient nitrogen detection and quality evaluation, and imposes minimal effects to environment. This technique has academic and realistic significance in developing the rapid measurement methods and pushing the frontier of quality testing in tea.

Key words: near infrared spectroscopy, green tea, total nitrogen content, sub-model

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