食品科学

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修饰改性β-葡聚糖溶液构象研究进展

高 洁,刘红芝,刘 丽,王 强*   

  1. 中国农业科学院农产品加工研究所,农业部农产品加工综合性重点实验室,北京 100193
  • 出版日期:2013-07-15 发布日期:2013-06-28
  • 通讯作者: 王 强
  • 基金资助:

    科技部国际合作重点项目(S2012ZR0302);国家自然科学基金面上项目(31171651)

Research Progress in the Conformation of Modified β-Glucan in Aqueous Solution

GAO Jie,LIU Hong-zhi,LIU Li,WANG Qiang*   

  1. Key Laboratory of Agro-products Processing, Ministry of Agriculture, Institute of Agro-products Processing Science and Technology,
    Chinese Academy of Agricultural Sciences, Beijing 100193, China
  • Online:2013-07-15 Published:2013-06-28
  • Contact: WANG Qiang

摘要:

在对葡聚糖研究的相关国内和国际文献进行统计分析的基础上,全面综述不同修饰改性方法对β-葡聚糖溶 液构象的影响,物理修饰改性方法主要包括超声波法、辐照法、微波法和其他方法,对β-葡聚糖在溶液中的构象影 响较小;化学修饰改性方法主要包括羧甲基化、硫酸酯化和磷酸酯化,使得β-葡聚糖链的柔顺性和刚性增加,在溶 液中呈较伸展的柔顺链、半刚性链或三螺旋链构象;生物修饰改性方法主要为β-葡聚糖酶法,改性后的燕麦β-葡 聚糖在溶液中呈无规线团构象。本文全面分析修饰改性β-葡聚糖溶液构象研究中存在的问题,并对今后的发展方 向进行展望。

关键词: &beta, -葡聚糖, 修饰改性, 构象转变

Abstract:

Based on the statistical analysis of relevant literature about glucan, the different effects on modified methods
affecting the conformation of β-glucan in aqueous solutions have been reviewed. The physical modified methods include
ultrasound, irradiation, microwave and other methods, which have less impact on the conformation of β-glucan in solution.
The chemical modified methods include carboxymethyl, sulfated and phosphoric esterification, which could increase the
flexibility and stiffness of β-glucan chain and cause the following conformations present in solution, extended flexible chain,
semi-stiff chain or triple helix chain. Biological modified methods mainly refer to enzymatic method. After β-glucanase
treatment, oat β-glucan exists as random coil in solution. Moreover, the existing problems in the research of modified β-glucan
conformation and its future development tendencies are proposed.

Key words: &beta, -glucan;modification;conformation transition

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