食品科学

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模拟条件下香辛类蔬菜对N-二甲基亚硝胺形成的影响

张 甜1,杨 华2,*   

  1. 1.山西农业大学食品科学与工程学院,山西 太谷 030801;2.天津农学院动物科学与动物医学学院,天津 300384
  • 出版日期:2017-01-15 发布日期:2017-01-16

Effects of Spicy Vegetables on the Formation of N-Nitrosodimethylamine under Simulated Conditions

ZHANG Tian1, YANG Hua2,*   

  1. 1. College of Food Science and Engineering, Shanxi Agricultural University, Taigu 030801, China;
    2. College of Animal Science and Veterinary Medicine, Tianjin Agricultural University, Tianjin 300384, China
  • Online:2017-01-15 Published:2017-01-16

摘要: 研究采用体外模拟条件及亚硝化反应体系,探究大葱、生姜、大蒜、洋葱4 种香辛类蔬菜的冻干粉及其可溶性组分干粉对N-二甲基亚硝胺(N-nitrosodimethylamine,NDMA)形成的影响。结果表明:香辛类蔬菜的种类和添加量、亚硝化反应体系的温度、时间等都对NDMA的形成表现出不同程度的促进或抑制作用。在模拟温度(腌制(4±1) ℃、室温(25±1) ℃、低温加工(80±1) ℃)条件下,大葱粉、洋葱粉及生姜粉均明显促进NDMA形成(P<0.05),且80 ℃时促进率最大;同一温度条件下,随反应时间延长,大葱粉和洋葱粉对NDMA形成的促进作用明显增强(P<0.05),生姜粉对NDMA形成没有显著影响(P>0.05);在同一温度同一反应时间内,随香辛类蔬菜粉添加量增加,对NDMA形成的促进作用显著增强(P<0.05)。但在4 ℃或25 ℃时,大蒜粉及生姜水溶性组分干粉对NDMA形成表现为抑制作用,其中生姜水溶性组分干粉抑制作用较弱(10%);在80 ℃时大蒜粉表现为促进NDMA的形成。实验说明4 类香辛类蔬菜在模拟条件下对NDMA的形成未能起到抑制作用。

关键词: 香辛类蔬菜, 模拟条件, N-二甲基亚硝胺

Abstract: The effects of lyophilized powder and water-soluble extract from spicy vegetables including green Chinese onion,
ginger, garlic and onion on the formation of N-nitrosodimethylamine (NDMA) were addressed under simulated conditions
in vitro and in nitrite reaction system. The results indicated that different types and amounts of spicy vegetables as well
as different reaction temperatures and times could promote or inhibit on the formation of NDMA. Green Chinese onion
powder, onion powder and ginger powder could significantly promote the formation of NDMA at simulated temperatures
of (4 ± 1) ℃ (for pickling), (25 ± 1) ℃ (room temperature), and (80 ± 1) ℃ (for processing) (P < 0.05), and they were the
most effective at 80 ℃. At the same temperature, the promotion of green onion powder and onion powder on the formation
of NDMA became significantly stronger with reaction time (P < 0.05), while ginger powder had no significant effect on the
formation of NDMA (P > 0.05). At the same temperature and reaction time, the promotion effect of spicy vegetables on the
formation of NDMA was significantly enhanced in a dose-dependent manner (P < 0.05). However, garlic powder and ginger
water-soluble extract exhibited an inhibition effect on the formation of NDMA at 4 or 25 ℃, and the latter (10%) was weaker
than the former. Garlic powder appeared to promote the formation of NDMA at 80 ℃. In conclusion, all four kinds of spicy
vegetables had no significant inhibitory effect on the formation of NDMA under simulated conditions.

Key words: spicy vegetable, simulated conditions, N-nitrosodimethylamine (NDMA)

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