食品科学 ›› 2021, Vol. 42 ›› Issue (10): 235-240.doi: 10.7506/spkx1002-6630-20200503-020

• 成分分析 • 上一篇    下一篇

气相色谱-离子迁移谱分析乳制品挥发性风味化合物

李娟,任芳,甄大卫,张浩,谢建春   

  1. (1.北京食品营养与人类健康高精尖创新中心,北京工商大学,北京 100048;2.山东海能科学仪器有限公司,山东 济南 251500;3.美国史蒂文森理工学院,美国 新泽西州 霍博肯 NJ 07030)
  • 出版日期:2021-05-25 发布日期:2021-06-02
  • 基金资助:
    “十三五”国家重点研发计划重点专项(2017YFD0400106);北京市自然科学基金面上项目(6172004)

Analysis of Volatile Flavor Compounds Dairy Products by Gas Chromatography-Ion Mobility Spectrometry

LI Juan, REN Fang, ZHEN Dawei, ZHANG Hao, XIE Jianchun   

  1. (1. Beijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Technology and Business University, Beijing 100048, China; 2. Shandong Hanon Subsidiary Company, Jinan 251500, China;3. Department of Chemistry and Biology, Stevens Institute of Technology, Hoboken NJ 07030, USA)
  • Online:2021-05-25 Published:2021-06-02

摘要: 采用气相色谱-离子迁移谱技术分析乳制品中挥发性风味化合物,样品包括2 个品牌巴氏杀菌乳、5 个品牌超高温瞬时灭菌乳和1 个品牌复原乳,共检出29 种化合物,主要有醛类、酮类、醇类、酯类及其他类,己酸甲酯、丁酸乙酯、乙酸异戊酯、乙酸乙酯、戊酸乙酯、1-戊醇、柠檬烯构成了巴氏杀菌乳中特征峰区域;糠醛、苯甲醛、4-甲基-2-戊酮、2-辛酮、1-丁醇、醋酸异丙酯构成了复原乳中特征峰区域;灭菌时产生的新挥发性化合物构成了超高温瞬时灭菌乳的特征峰区域。主成分分析处理,不同类型或不同品牌乳制品得到明显区分,表明气相色谱-离子迁移谱分析可为不同乳制品的判别区分提供可能。

关键词: 气相色谱-离子迁移谱;乳制品;挥发性风味化合物;判别区分

Abstract: Gas chromatography-ion mobility spectrometry (GC-IMS) was used to analyze the volatile flavor compounds different dairy products, including two brands of pasteurized milk, five brands of ultra-high-temperature sterilized milk and one brand of reconstituted milk. A total of 29 compounds were identified, mainly aldehydes, ketones, alcohols, esters, and others. Methyl hexanoate, ethyl butanoate, 3-methylbutyl acetate, ethyl acetate, ethyl pentanoate, 1-pentanol, and limonene constituted the characteristic peak region of pasteurized milk; furfural, benzaldehyde, methyl isobutyl ketone, 2-octanone, 1-butanol, and isopropyl acetate constituted the characteristic peak region of reconstituted milk; and new volatile compounds generated by sterilization constituted the characteristic peak region of ultra-high-temperature sterilized milk. By means of principal component analysis (PCA), the different types or brands of dairy products were clearly classified. This study indicates the usefulness of GC-IMS to discriminate different dairy products.

Key words: gas chromatography-ion mobility spectrometry; dairy products; volatile flavor compounds; discrimination

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