食品科学 ›› 2007, Vol. 28 ›› Issue (5): 81-85.

• 基础研究 • 上一篇    下一篇

三种磷脂对Maillard模型体系产生的主要含硫挥发性化合物的影响

 张慧丽, 田红玉, 孙宝国   

  1. 北京工商大学化学与环境工程学院; 北京工商大学化学与环境工程学院 北京100037; 北京100037;
  • 出版日期:2007-05-15 发布日期:2011-12-31

Effects of Three Phospholipids on Sulfur-containing Volatile Components in Maillard Model Systems

 ZHANG  Hui-Li, TIAN  Hong-Yu, SUN  Bao-Guo   

  1. The College of Chemistry and Environment Engineering,Beijing Technology and Business University,Beijing 100037,China
  • Online:2007-05-15 Published:2011-12-31

摘要: 本实验研究了三种磷脂对Maillard模型体系产生的主要含硫挥发性产物的影响。分别将三种磷脂加入到L-半胱氨酸与D-核糖组成的Maillard模型体系中,在140℃下加热1h,产物通过二氯甲烷萃取,利用GC-MS分析,比较各挥发性成分中主要含硫化合物的种类和产量。分析结果表明,加入磷脂后的Maillard反应体系能产生更好的肉香味。Maillard反应挥发性产物中酰基噻吩类、杂环硫醇类、噻吩酮类、双环噻吩类、巯基酮类以及部分噁唑类减少。磷脂氧化降解产物与Maillard反应中间体发生反应,形成一些新的挥发性产物,包括部分2-烷基噻吩、烯基噻吩、噻喃以及脂肪硫醇等。

关键词: Maillard模型反应, 磷脂, 含硫挥发性化合物, L-半胱氨酸, D-核糖

Abstract: In order to improve the phospholipids application in meat flavor,the effects of three phospholipids to the sulfur- containing volatile components in Maillard model systems were studied.Three phospholipids were added into the Maillard reaction models made of L-cysteine and D-ribose,heated at 140℃for 1 h.The products were extracted by CH2Cl2,and were analyzed by GC-MS.The Maillard reaction system including phospholipids showed better meaty flavor.Many of the volatile products of Maillard reaction were decreased due to the effects of phospholipids,including acylthiophenes,heterocyclic thiols, thiophenones,bicyclic-compounds,mercaptocarbonyls and a few oxazoles.The reaction of oxidative products of phospholip- ids with the intermediates of Maillard reaction gives forth 2-alkylthiophene,alkenylthiophene,pentylthiapyran,alkanethiols and others.

Key words: Maillard reaction, phospholipids, sulfur-containing volatile components, L-cysteine, D-ribose