食品科学 ›› 2026, Vol. 47 ›› Issue (2): 10-20.doi: 10.7506/spkx1002-6630-20250828-193

• 食品安全快速检测专栏 • 上一篇    下一篇

荧光共价/金属有机骨架纳米材料在食品中农药残留检测的研究进展

张瑛,郝瑞新,白宝清,张锦华,薄涛,杨钰昆   

  1. (山西大学生命科学学院,山西 太原 030006)
  • 出版日期:2026-01-25 发布日期:2026-02-05
  • 基金资助:
    山西省基础研究(自由探索类)青年项目(202403021222017); 中央政府引导地方科技发展基金项目(YDZJSX2025D009);国家自然科学基金面上项目(32072301)

Research Progress on Fluorescent Covalent/Metal-Organic Frameworks for Pesticide Residue Detection in Foods

ZHANG Ying, HAO Ruixin, BAI Baoqing, ZHANG Jinhua, BO Tao, YANG Yukun   

  1. (School of Life Science, Shanxi University, Taiyuan 030006, China)
  • Online:2026-01-25 Published:2026-02-05

摘要: 农药在农业生产的保产保量方面发挥着十分重要的作用,但其不易降解及长期广泛施用也引起了不容忽视的食品安全问题。建立灵敏度和准确度双高的快速农药残留分析技术,是实现我国食品安全监管、公共卫生监测及智慧农业建设的重要支撑。基于荧光共价有机骨架(covalent organic frameworks,COFs)和金属有机骨架(metal-organic frameworks,MOFs)的分析技术具有灵敏度高、检测速度快及易于操作的优点,是目前现场快速检测的研究前沿和热点之一。基于此,本文重点对近5 年来COFs和MOFs荧光纳米材料在食品中农药残留快速检测中的研究进展进行回顾。首先从COFs和MOFs荧光发光原理角度出发,详述荧光COFs和MOFs的设计策略。其次,介绍其在食品领域中农药残留快速检测的应用进展。最后,展望该技术的发展趋势并对亟待解决的问题进行讨论,旨在为基于荧光COFs和MOFs快速检测农药残留技术的发展提供新思路。

关键词: 食品安全;农药残留;荧光检测;共价有机骨架;金属有机骨架

Abstract: Pesticides are vital for maintaining agricultural output, but their non-degradability and wide applications have raised significant concerns regarding food safety and human health. The development of sensitive and accurate methods for analyzing pesticide residues is crucial for achieving food safety regulation, public health surveillance, and smart agricultural construction in China. Covalent organic frameworks (COFs) and metal-organic frameworks (MOFs)-based fluorescence detection methods offer advantages like heightened sensitivity, rapid detection speed, and operational simplicity, positioning them as one of the frontiers and hotspots in on-site rapid detection. This paper aims to review the research progress on COFs and MOFs-based fluorescence detection methods for pesticide residues in foods over the last five years. First, starting with the principles of fluorescent emission in COFs and MOFs, their design methodologies are elaborated. Next, the current status of the application of fluorescent COFs and MOFs in the detection of pesticide residues in foods is reviewed. Ultimately, the future trends and challenges are discussed. This review will provide a new idea for developing rapid detection techniques based on fluorescent COFs and MOFs for pesticide residue detection.

Key words: food safety; pesticide residues; fluorescence detection; covalent organic frameworks; metal-organic frameworks

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