食品科学 ›› 2022, Vol. 43 ›› Issue (8): 22-28.doi: 10.7506/spkx1002-6630-20210131-373

• 食品化学 • 上一篇    

纳米SiO2改性4 种大分子材料的乳液制备及性质

赵国瑜,范方宇,黄瑾,李华珊,杨丝蕾   

  1. (西南林业大学生命科学学院,西南山地森林资源保育与利用教育部重点实验室,云南 昆明 650224)
  • 发布日期:2022-04-26
  • 基金资助:
    国家自然科学基金地区科学基金项目(31760470);云南省“万人计划”青年拔尖人才专项(YNWR-QNBJ-2018-046)

Preparation and Properties of Emulsions Stabilized with Four Kinds of Nano-SiO2-Modified Macromolecular Material

ZHAO Guoyu, FAN Fangyu, HUANG Jin, LI Huashan, YANG Silei   

  1. (Key Laboratory for Forest Resources Conservation and Utilization in the Southwest Mountains of China, Ministry of Education, College of Life Science, Southwest Forestry University, Kunming 650224, China)
  • Published:2022-04-26

摘要: 为提高乳液稳定性,采用纳米SiO2改性明胶(gelatin,GE)、大豆分离蛋白、壳聚糖和阿拉伯胶(gum arabic,GA)制备茶油乳液。以乳化活性、乳化稳定性、离心稳定性、平均粒径、流变特性为考察指标,探究质量分数3.000%的纳米SiO2对4 种大分子材料复合乳液性质的影响,并对乳液的微观结构及油滴分布进行观察。结果表明,纳米SiO2能增强乳液稳定性,其中GE-纳米SiO2复合乳液综合性质最佳。添加纳米SiO2后乳化活性和乳化稳定性显著增加(P<0.05),离心稳定性降低68.444%。平均粒径为8.472 μm,乳液粒径最小且分布均匀,表面光滑呈球状。流变表现为典型的弱凝胶特性,稳定性良好。研究结果可为天然高分子和纳米SiO2乳液的制备和应用提供实践基础。

关键词: 纳米SiO2;乳液;大分子材料;茶油;稳定性

Abstract: In order to improve the stability of emulsions, gelatin (GE), soybean protein isolate (SPI), chitosan (CS) and gum arabic (GA) were modified with 3.000% nano-SiO2 and used separately as a stabilizer to prepare camellia oil emulsions. The effect of nano-SiO2 on emulsion properties was investigated by considering emulsifying activity, emulsion stability, centrifugal stability, average particle size, rheological properties, microstructure and oil droplet distribution. The results showed that nano-SiO2 enhanced the stability of emulsions. The comprehensive properties of GE-nano-SiO2 composite emulsion were the best. Addition of nano-SiO2 significantly enhanced the emulsifying activity and emulsion stability (P < 0.05), and reduced the centrifugal stability by 68.444%. The resulting emulsion had the smallest particle size and uniform particle size distribution with an average particle size of 8.472 μm, and the emulsion particles were spherical with smooth surface. The emulsion was rheologically characterized as a typical weak gel with good stability. The results of this study could provide a practical basis for the preparation and application of nano-SiO2-modified natural macromolecules in emulsions.

Key words: nano-SiO2; emulsion; macromolecular materials; camellia oil; stability

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