Ultra-performance Liquid Chromatography-Tandem Mass Spectrometry for the Determination of Benzimidazoles Residues in Apples

doi:10.7506/spkx1002-6630-200912046

FOOD SCIENCE ›› 2009, Vol. 30 ›› Issue (12): 209-212.doi: 10.7506/spkx1002-6630-200912046

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Ultra-performance Liquid Chromatography-Tandem Mass Spectrometry for the Determination of Benzimidazoles Residues in Apples

ZHAO Ling-jun1，YUE Hui2，GUO Dong-liang2，CUI Jin3，ZHAO Shan-cang2

(1. Jinan Agriculture Information Center, Jinan 250002, China；2. Inspection Center of Food Quality (Jinan), Ministry of
Agricalture, Jinan 250100, China；3. Laiwu Product Quality Supervision and Inspection Institute, Laiwu 271100, China)

Received:2008-09-05 Revised:2008-12-12 Online:2009-06-15 Published:2010-12-29
Contact: ZHAO Ling-jun1， E-mail:lingly_zhao@yahoo.com

Abstract

Abstract:

Objective: To establish a method for determination of benzimidazoles residues in apples by UPLC-MS/MS. Methods: Sample was extracted with acetonitrile. After impurity removal by NaCl salting out, the sample was filtered through a membrane (0.2 μm), and injected into UPLC column. Identification was achieved by electrospray ionization in positive mode (ESI+) using multiple reaction monitoring (MRM). Results: The detection limits for carbendazim, thiabendazol, thiophanatemethyle were 0.17, 0.16, 0.07 μg/kg, respectively; the average recoveries for the three benzimidazoles in blank sample spiked at three levels (1.0, 5.0 and 10.0 μg/kg) were in the range of 89.2%－104.6%, and the RSDs were 1.7%－3.6% (n = 6). Conclusion: The method can completely meet the requirement of analysis for benzimidazoles residues in apples.

Key words: UPLC-MS/MS, apple, benzimidazole, residue

CLC Number:

TS207.53

ZHAO Ling-jun1，YUE Hui2，GUO Dong-liang2，CUI Jin3，ZHAO Shan-cang2. Ultra-performance Liquid Chromatography-Tandem Mass Spectrometry for the Determination of Benzimidazoles Residues in Apples[J]. FOOD SCIENCE, 2009, 30(12): 209-212.

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Ultra-performance Liquid Chromatography-Tandem Mass Spectrometry for the Determination of Benzimidazoles Residues in Apples

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