食品科学 ›› 2011, Vol. 32 ›› Issue (7 ): 77-82.doi: 10.7506/spkx1002-6630-201107018

• 基础研究 • 上一篇    下一篇

莲房原花青素的稳定性及热降解动力学研究

汪志慧,孙智达*,谢笔钧   

  1. 华中农业大学食品科技学院
  • 收稿日期:2010-09-09 修回日期:2011-02-17 出版日期:2011-04-15 发布日期:2011-03-30
  • 通讯作者: 汪志慧 E-mail:wangzhihui100@yahoo.cn
  • 基金资助:
    国家“863”计划项目(2007AA100401)

Stability and Thermal Degradation Kinetics of Procyanidins from Lotus Seed Pods

WANG Zhi-hui,SUN Zhi-da*,XIE Bi-jun   

  1. College of Food Science and Technology, Huazhong Agricultural University, Wuhan 430070, China
  • Received:2010-09-09 Revised:2011-02-17 Online:2011-04-15 Published:2011-03-30
  • Contact: WANG Zhi-hui E-mail:wangzhihui100@yahoo.cn

摘要: 对莲房原花青素(LSPC)的稳定性和热降解动力学进行研究。结果表明:LSPC在低温、避光和弱酸条件下能表现出良好的稳定性;NaCl、蔗糖、葡萄糖等食品原料和防腐剂对LSPC的稳定性影响不明显;H2O2对莲房原花青素破坏作用较大,NaHSO3和VC对其有保护作用;Fe3+、Fe2+、Pb2+和Al3+对LSPC有明显的破坏作用,其他金属离子影响不大;4种不同灭菌方式对LSPC的稳定性有不同程度影响,其中巴氏灭菌的影响较小,高压蒸汽灭菌的影响最大。LSPC的热降解符合动力学一级反应,其反应活化能Ea为43.10kJ/mol,反应常数k0为1.51×105,获得LSPC降解的预测模型。经验证,模型与实测值拟合较好,表明该模型是合理的。

关键词: 莲房, 原花青素, 稳定性, 降解动力学

Abstract: Lotus seed pod procyanidins (LSPCs) were extracted with 70% aqueous ethanol solution and purified by AB-8 macroporous resin adsorption, and their stability and thermal degradation kinetics were investigated. LSPCs were found to be very stable under low temperature, light-avoiding and weakly acidic conditions. NaCl, sucrose and glucose and the preservatives sodium benzoate and potassium sorbate had no obvious effect on LSPCs. H2O2 exhibited a great destructive effect on LSPCs, while NaHSO3 and VC had protective effect. LSPCs could be damaged by Fe3+, Fe2+, Pb2+ and Al3+, and other tested metal ions had a small effect. Four different sterilization methods were found to affect the stability of LSPCs to different extents, of which pasteurization had the least effect and high pressure steam sterilization had the largest effect. The thermal degradation of LSPCs complied with the first-order reaction kinetic process, and the activation energy Ea, and reaction constant k0 were 43.10 kJ/mol and 1.51×105, respectively. Moreover, a prediction model for the degradation of LSPCs was established. In validation experiments, the experimental results were observed to be in good consistency with the predicted ones, indicating that the prediction model is reasonable. 

Key words: lotus seed pod, procyanidins, stability, degradation kinetics

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