食品科学 ›› 2009, Vol. 30 ›› Issue (13): 64-67.doi: 10.7506/spkx1002-6630-200913014

• 基础研究 • 上一篇    下一篇

微波条件下聚烯烃抗氧剂向食用油迁移的扩散系数研究

刘志刚1 , 2,卢立新1 , 2,王志伟3,刘全校4,许文才4   

  1. 1. 江南大学包装工程系 2. 中国包装总公司食品包装技术与安全重点实验室 3. 暨南大学珠海学院 4. 北京印刷学院 印刷包装材料与技术北京市重点实验室
  • 收稿日期:2008-11-07 修回日期:2009-02-04 出版日期:2009-07-01 发布日期:2010-12-29
  • 通讯作者: 刘志刚 E-mail:Liuzg0000@yahoo.com.cn
  • 基金资助:

    广东省自然科学基金项目(07005952);印刷包装材料与技术北京市重点实验室开放课题(KF200806);
    江南大学引进人才科研启动基金项目;江南大学青年基金项目(2007LQN19)

Calculation of Diffusion Coefficient of 3 Polyolefin Antioxidants Migrating into Edible Oils under Microwave Conditions

LIU Zhi-gang1,2,LU Li-xin1.2,WANG Zhi-wei3,LIU Quan-xiao4,XU Wen-cai4   

  1. 1. Department of Packaging Engineering, Jiangnan University, Wuxi 214122, China;2. Key Laboratory of Food Packaging
    Techniques and Safety, China National Packaging Corporation, Wuxi 214122, China;3. Zhuhai College, Jinan University,
    Zhuhai 519070, China;4. Beijing Key Laboratory of Printing and Packaging Materials and Technology, Beijing Institute of
    Graphic Communication, Beijing 102600, China
  • Received:2008-11-07 Revised:2009-02-04 Online:2009-07-01 Published:2010-12-29
  • Contact: LIU Zhi-gang E-mail:Liuzg0000@yahoo.com.cn

摘要:

实验研究不同微波加热功率条件下PE膜内三种不同分子量不同分子结构的抗氧化剂(BHT、Irganox 1076和Irgafos 168)向6 种食用油的迁移,计算相应的扩散系数并给出其与微波加热功率的关系图。鉴于微波加热条件下迁移的特殊性,提出构建新的扩散系数预测模型的设想。

关键词: 扩散系数, 微波加热, 迁移, 聚烯烃, 抗氧化剂

Abstract:

This study investigated the migrations of 3 polyolefin antioxidants including BHT, Irganox 1076 and Irgafos 168 with different molecular weights (MWs) and chemical structures in PE films into 6 kinds of edible oils under microwave radiation of 100 W power for different periods of time, and calculated the average diffusion coefficients of the 3 polyolefin antioxidants migrating into 6 kinds of edible oils under microwave radiation of different powers. The results indicated that the migrations of the antioxidants from PE into edible oils elevated with the increase of microwave power and the prolongation of treatment time. No significant correlations were found between the average diffusion coefficients of the antioxidants and their MWs. However, the differences in relationships between diffusion coefficient and microwave power were observed for the 3 antioxidants. A hypothesis for construction of new models for predicting the diffusion coefficient was proposed based on the particularity of migration under microwave radiation.

Key words: diffusion coefficient, microwave heating, migration, polyolefin, antioxidants

中图分类号: