食品科学

• 分析检测 • 上一篇    下一篇

基于羟基价检测地沟油方法构建

莫一鸣,李日宗,林章凛   

  1. 清华大学化学工程系,北京 100084
  • 出版日期:2013-07-25 发布日期:2013-08-02

Identification of Waste Edible Oil Based on Hydroxyl Value

MO Yi-ming,LI Ri-zong,LIN Zhang-lin   

  1. Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
  • Online:2013-07-25 Published:2013-08-02

摘要:

针对现存的地沟油检测方法的缺陷,从理论上分析了地沟油精炼过程中不易被除去的物质,根据不易被除去的物质中含有羰基和羟基的原理设计通过测定油样品中羰基价和羟基价鉴别地沟油的方法。结果表明:经使用的油的羟基价均明显高于常用食用油,即使是精制地沟油的羟基价也是常用食用油的三倍多,因此羟基价是一个特异性较强的检测指标。

关键词: 地沟油, 羟基价, 甘油二酯, 综合指标体系

Abstract:

Although detection methods for waste edible oil are currently available, these methods have defects. According
to our theoretical analysis, those materials which are hard to remove during refining of waste edible oil contain carbonyl or
hydroxyl groups. In this study, two methods were presented to identify waste edible oil by measuring carbonyl and hydroxyl
values, respectively. Used cooking oils had an obviously higher hydroxyl value than fresh ones. There was an over three-fold
increase in the hydroxyl value as compared with the fresh cooking oils, even though the used cooking oils were refined. Thus
hydroxyl value is a specific indicator to identify waste edible oil.

Key words: waste edible oil, hydroxyl value, diglyceride, comprehensive detection index system