食品科学 ›› 2022, Vol. 43 ›› Issue (4): 257-263.doi: 10.7506/spkx1002-6630-20210203-062

• 成分分析 • 上一篇    下一篇

基于GC-IMS和电子鼻技术分析贮酒容器对凤香型白酒香气成分的影响

刘丽丽,杨辉,荆雄,徐晨,张亚芳,阎宗科,祁耀华   

  1. (1.陕西科技大学食品与生物工程学院,陕西 西安 710021;2.陕西西凤酒股份有限公司,陕西 宝鸡 721000)
  • 出版日期:2022-02-25 发布日期:2022-03-08

Influence of Different Storage Containers on the Aroma Composition of Fengxiang-type Baijiu Analyzed by Gas Chromatography-Ion Mobility Spectroscopy and Electronic Nose

LIU Lili, YANG Hui, JING Xiong, XU Chen, ZHANG Yafang, YAN Zongke, QI Yaohua   

  1. (1. School of Food and Biological Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China; 2. Shaanxi Xifeng Liquor Co. Ltd., Baoji 721000, China)
  • Online:2022-02-25 Published:2022-03-08

摘要: 为研究贮酒容器对凤香型白酒香气成分的影响,采用电子鼻与气相色谱离子迁移谱(gas chromatography-ion mobility spectrometry,GC-IMS)技术对不同容器贮存的凤香型白酒风味物质及理化指标——乙醇体积分数、总酸、总酯、可溶性固形物质量浓度及pH值进行分析和比较,以期为凤香型白酒贮存工艺的改进提供参考。电子鼻和GC-IMS分析结果均表明:新产酒与贮酒香气特征有显著差别,陶坛与不锈钢罐贮酒风格相似,而酒海贮酒风格独特。GC-IMS在4 类酒样中共检测出66 种挥发性成分,主要为酯类、醛类、酮类、醇类物质;不锈钢罐和陶坛贮酒中乙醇酯类、双乙酰、1-丙醇等物质相对含量较高,在酒海贮酒中含有较多的高级醇酯类、醛酮类等物质;酒海贮酒中具有最低总酸质量浓度,最高可溶性固形物质量浓度、乙醇体积分数和最高的pH值。

关键词: 电子鼻;气相色谱离子迁移谱;酒海;陶坛;白酒

Abstract: In order to explore the effect of storage containers on the aroma components of Fengxiang-type Baijiu, gas chromatography-ion mobility spectrometry (GC-IMS) and electronic nose (E-nose) were used to analyze and compare the flavor components and physicochemical properties such as alcohols, total acids, total esters, soluble solids content (SSC) and pH of Baijiu samples stored in different containers. The results showed that the aroma characteristics of newly produced and stored Baijiu samples were greatly different from each other. Specifically, the aroma characteristics of Baijiu samples stored in a pottery jar were similar to those stored in a stainless-steel vessel, while the aroma characteristics of Juihai-stored Baijiu were unique. By GC-IMS, a total of 66 volatile components were identified in the four Baijiu samples, mainly including esters, aldehydes, ketones and alcohols. Baijiu samples stored in the pottery jar and in the stainless-steel vessel had higher contents of ethanol esters, 2,3-pentanedione and 1-propanol, whereas Jiuhai-stored samples contained higher contents of higher alcohol esters, aldehydes, ketones and some other substances, and had the lowest total acid concentration and the highest SSC, alcohol concentration and pH among the four samples.

Key words: electronic nose; gas chromatography-ion mobility spectrometry; Jiuhai; pottery jars; Baijiu

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