食品科学

• 基础研究 •    下一篇

ε-聚赖氨酸与羧甲基纤维素钠的相互作用

冯李院1,关郁芳2,颜才植1,叶发银1,3,赵国华1,3,*   

  1. 1.西南大学食品科学学院,重庆 400715;2.贵州省农业科学院 贵州生物技术研究所,贵州 贵阳 550006;
    3.重庆市特色食品工程技术研究中心,重庆 400715
  • 出版日期:2016-04-15 发布日期:2016-04-13

Interaction between Sodium Carboxymethyl Cellulose and ε-Polylysine

FENG Liyuan1, GUAN Yufang2, YAN Caizhi1, YE Fayin1,3, ZHAO Guohua1,3,*   

  1. 1. College of Food Science, Southwest University, Chongqing 400715, China;
    2. Guizhou Institute of Biotechnology, Guizhou Academy of Agricultural Sciences, Guiyang 550006, China;
    3. Chongqing Engineering Research Center of Regional Food, Chongqing 400715, China
  • Online:2016-04-15 Published:2016-04-13

摘要:

以ε-聚赖氨酸(ε-polylysine,ε-PL)与羧甲基纤维素钠(sodium carboxymethylcellulose,CMC-Na)相互作用体系的混浊度、Zeta电位和粒度为指标,研究了CMC-Na的取代度(degree of substitution,DS)和相对分子质量对ε-PL/CMC-Na相互作用体系的影响。结果表明,在pH 4.0时,ε-PL与CMC-Na之间的静电相互作用主要依赖于ε-PL氨基与CMC-Na羧基的物质的量比;同时,CMC-Na的取代度和相对分子质量均对ε-PL/CMC-Na相互作用具有显著影响,且CMC-Na取代度对体系稳定性的影响更大。

关键词: &epsilon, -聚赖氨酸, 羧甲基纤维素钠, Zeta电位, 取代度

Abstract:

The interaction between food ingredients is one of the research focuses in food science. ε-Polylysine (ε-PL),
as a food additive, is a cationic polyelectrolyte with excellent antimicrobial properties, and it can interact with anionic
polymers such as sodium carboxymethylcellulose (CMC-Na) to affect its antimicrobial properties and the stability of related
food systems. In this study, the effects of degree of substitution (DS) and molecular weight of CMC-Na on the interaction
between ε-PL and CMC-Na as indicated by turbidity, Zeta potential and particle size were investigated. Results revealed that
the electrostatic interaction between ε-PL and CMC-Na mainly depended on the molar ratio of cationic amino groups in ε-PL
to carboxyl anion groups in CMC-Na. In addition, both DS and molecular weight of CMC-Na exerted a serious impact on
the interaction between ε-PL and CMC-Na and the effect of DS was more significant.

Key words: ε-polylysine, sodium carboxymethylcellulose, Zeta potential, degree of substitution

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