食品科学 ›› 2010, Vol. 31 ›› Issue (3): 74-78.doi: 10.7506/spkx1002-6300-201003016

• 基础研究 • 上一篇    下一篇

蔗糖含量对牡丹花色苷热稳定性和降解动力学的影响

樊金玲1,朱文学1 ,* ,巩卫东2,沈军卫1,韩江南1,马海乐1,郭秉印1   

  1. 1.河南科技大学食品与生物工程学院 2.河南出入境检验检疫局检验检疫技术中心洛阳分中心
  • 收稿日期:2009-04-07 出版日期:2010-02-01 发布日期:2010-12-29
  • 通讯作者: 朱文学 E-mail:wutao1990@yahoo.com.cn;fan20032006@yahoo.com.cn
  • 基金资助:

    洛阳市科技攻关计划项目(983023);河南省教育厅自然科学研究计划项目(2009B180005)

Effect of Sucrose on Thermal Stability and Degradation Kinetics of Peony Anthocyanins

FAN Jin-ling1,ZHU Wen-xue1,*,GONG Wei-dong2,SHEN Jun-wei1,HAN Jiang-nan1,MA Hai-le1,GUO Bing-yin1   

  1. 1. College of Food and Bioengineering, Henan University of Science and Technology, Luoyang 471003, China;
    2. Luoyang Branch of Inspection and Quarantine Technology Centre, Henan Entry-Exit Inspection and Quarantine Bureau, Luoyang
    471003, China
  • Received:2009-04-07 Online:2010-02-01 Published:2010-12-29
  • Contact: ZHU Wen-xue E-mail:wutao1990@yahoo.com.cn;fan20032006@yahoo.com.cn

摘要:

研究了蔗糖含量对牡丹花色苷热稳定性和降解动力学的影响。结果表明:牡丹花色苷的热降解符合一级反应动力学模型,花色苷半衰期随加热温度升高而缩短;花色苷样品液所含的4 种花色苷中,降解速率依次为矢车菊-3-O- 二葡萄糖>芍药-3-O- 葡萄糖苷>矢车菊-3, 5-O- 二葡萄糖苷>芍药-3, 5-O- 二葡萄糖苷;花色苷样品液的褐变指数随加热温度的升高和加热时间的延长而增大。蔗糖抑制了花色苷的降解,表现为提高了花色苷样品液的吸光度,降低了褐变指数;抑制程度与蔗糖浓度、加热处理的时间和温度有关;但含糖体系花色苷的热降解不符合一级反应动力学。

关键词: 花色苷, 热稳定性, 褐变, 降解动力学, 蔗糖, 牡丹

Abstract:

In this work, thermal stability and degradation kinetics of peony anthocyanins were investigated under various sucrose concentrations (11, 30, 45 or 62°Brix) during heating. Results indicated that thermal degradation kinetic model of peony anthocyanins was a first-order degradation kinetic process. The half-life of anthocyanin degradation was shortened due to increased temperature. During the degradation process of anthocyanin monomers in solution, the degradation rate exhibited a drop order of cyanidin-3-O-glucoside > peonidin-3-O-glucoside >cyanidin-3,5-di-O-glucoside > peonidin-3,5-di-O-glucoside. Degradation of anthocyanins exhibited a decrease trend with increasing sucrose concentration during heating. However, the thermal degradation of anthocyanins did not obey the first-order kinetic model. In addition, the browning index was increased with increasing temperature and heating time. However, the degradation of anthocyanins with sucrose revealed the lower browning index than the sample without sucrose. These results suggest that the presence of sucrose reduces anthocyanin degradation in time-, temperature- and concentration-dependent manners.

Key words: anthocyanin, thermal stability, browning, degradation kinetics, sucrose, peony

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