食品科学

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枇杷果皮热风干燥前后功能性成分含量变化与挥发性成分分析

张 巧1,顾欣哲1,吴永进2,屠 康1,*   

  1. ZHANG Qiao1, GU Xinzhe1, WU Yongjin2, TU Kang1,*
  • 出版日期:2016-08-25 发布日期:2016-08-30
  • 通讯作者: 屠 康
  • 基金资助:

    公益性行业(农业)科研专项(201303088-03)

Analysis of Functional Components and Volatile Components from Loquat Peel Before and After Hot-Air Drying

ZHANG Qiao1, GU Xinzhe1, WU Yongjin2, TU Kang1,*   

  1. 1. College of Food Science and Technology, Nanjing Agricultural University, Nanjing 210095, China;
    2. Zhejiang Taizhou Yiguan Food Co. Ltd., Taizhou 318020, China
  • Online:2016-08-25 Published:2016-08-30
  • Contact: TU Kang

摘要:

研究热风干燥对枇杷果皮中功能性成分(多酚、黄酮、三萜酸)及果皮挥发性成分的影响。用60 ℃热风干燥将枇杷果皮烘干至水分含量为9%~10%后,测定干燥前后功能性成分的含量,并利用顶空固相微萃取结合气相色谱-质谱联用分析和鉴定挥发性成分及相对含量。结果显示,干燥后枇杷果皮中的总多酚((37.94±0.84) mg GAE/g)和总黄酮((19.29±0.76) mg Rutin/g)的含量较新鲜果皮(总多酚:(63.66±1.68) mg GAE/g;总黄酮:(56.78±1.44) mg Rutin/g)显著减少(P<0.05),总三萜酸含量变化不显著;在新鲜果皮中检测到35 种挥发性成分,主要是醛、酯、酮,其中己醛(相对含量19.79%)和反-2-己烯醛(相对含量26.59%)为主要挥发性成分。与新鲜枇杷皮相比,热风干燥增加了挥发性成分的种类,共检测到73 种挥发性成分,主要是醛、酯、酮,与新鲜果皮共有的成分有21 种。壬醛(相对含量31.47%)为干样中的主要挥发性成分,其他相对含量较高的成分为β-环柠檬醛、β-紫罗酮、二氢猕猴桃内酯、癸醛等,这些成分共同构成了干燥果皮的特有香气。

关键词: 枇杷果皮, 热风干燥, 多酚, 黄酮, 三萜酸, 挥发性成分

Abstract:

In this research study, we determined the effect of hot-air drying on three functional components (polyphenols,
flavonoids and triterpene acids) and volatile components of loquat peel. Fresh samples of loquat peel were hot-air dried 60 ℃
to a moisture of 9%–10% to investigate changes in the contents of functional components before and after the drying
process. The identification and quantitation of volatile components by using headspace solid phase microextraction coupled
with gas chromatography-mass spectrometry (HS-SPME-GC-MS). Results illustrated that the contents of polyphenols and
flavonoids in dried loquat peel were significantly lower than in fresh loquat peel (P < 0.05), which were (37.94 ± 0.84) and
(19.29±0.76) mg/g vs. (63.66 ± 1.68) and (56.78 ± 1.44) mg/g, respectively. On the other hand, no significant change in
triterpene acids was noted. Totally, 35 volatile compounds were detected in fresh loquat peel, mainly aldehydes, esters,
ketones, which were dominated by hexanal (19.79%) and trans-2-hexenal (26.59%). In comparison with fresh loquat
peel, hot-air drying resulted in the formation of new volatiles as indicated by increasing the number of volatiles identified
to 73, which mainly included aldehydes, esters and ketones. Twenty-one volatile compounds were common to both
samples. Nonanal (31.47%) was the most dominant volatile of the dried sample, followed by β-cyclocitral, β-ionone,
dihydroactinidiolide and decanal, which altogether contributed to the distinct aroma of the dried loquat peel.

Key words: loquat peel, hot-air drying, polyphenol, flavonoid, triterpene acid, volatile components

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