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Determination of Iodine in Table Salt by Surfactant Sensitization Spectrophotometric Method

LIU Dong-lian1, SHEN Tian-jiao2, LIU Li-hua1, LIU Hui-yuan1,*   

  1. 1. Department of Chemistry, Tangshan Normal College, Tangshan 063000, China;
    2. School of Public Health, Harbin Medical University, Harbin 150081, China
  • Online:2014-06-25 Published:2014-07-03
  • Contact: LIU Hui-yuan

Abstract:

This paper describes a method for the determination of iodine in table salt using iodate-fluorescent yellowsurfactant
system. The conditions for the oxidation of fluorescent yellow by potassium iodate in acetic medium were studied.
The system had a maximum absorption at 438.5 nm in the medium of acetic acid. Beer’s law was obeyed in the range of
0.40–3.00 mg/L of iodine. The molar absorption coefficient was 4.31×104 L/(mol·cm) with a correlation coefficient of
0.999 0. The precision expressed as relative standard deviation (RSD) was in the range of 0.83%–1.47%, and the recoveries
were in the range of 98.1%–98.4%. This method is simple, rapid, accurate and precise, and has been successfully used in
determination of iodine in table salt.

Key words: fluorescent yellow, fade spectrophotometric method, surfactant, iodine, table salt

CLC Number: