食品科学 ›› 2017, Vol. 38 ›› Issue (11): 64-68.doi: 10.7506/spkx1002-6630-201711011

• 基础研究 • 上一篇    下一篇

白杨素对蒜氨酸美拉德反应的影响

杜阳敏,周 华,黎海梅,欧仕益,晏日安   

  1. 暨南大学理工学院,广东 广州 510632
  • 出版日期:2017-06-15 发布日期:2017-06-19

Effect of Chrysin on Maillard Reaction of Alliin

DU Yangmin, ZHOU Hua, LI Haimei, OU Shiyi, YAN Ri’an   

  1. College of Science and Engineering, Jinan University, Guangzhou 510632, China
  • Online:2017-06-15 Published:2017-06-19

摘要: 以化学合成的蒜氨酸为原料,研究白杨素对蒜氨酸美拉德反应的影响。结果表明,在一定反应条件下,白杨素可能轻微促进蒜氨酸与果糖美拉德反应体系中羟甲基糠醛物质的生成;在反应初期,白杨素可以部分抑制蒜氨酸的分解,其分解率仅有10.1%,而空白对照体系的分解率接近25.0%,分解产物主要为二烯丙基硫醚,但到反应后期,白杨素对蒜氨酸分解的影响较弱,蒜氨酸的最终分解率达到68.2%,分解产物为二烯丙基硫醚、二烯丙基二硫醚、二烯丙基三硫醚等混合物;羟甲基糠醛对蒜氨酸的分解具有显著的促进作用,反应5 h后,蒜氨酸的分解率接近100%,推测羟甲基糠醛在蒜氨酸的分解中可能扮演了催化剂的角色。

关键词: 白杨素, 蒜氨酸, 羟甲基糠醛, 美拉德反应

Abstract: The effect of chrysin on the Maillard reaction between synthetic alliin and fructose was investigated. The results showed that chrysin could slightly increase the production of hydroxymethyl furfural (HMF). It was found that chrysin inhibited the decomposition of alliin with a decomposition percentage of only 10.1% compared with 25.0% for the control. In the earlier stage of the reaction, chrysin facilitated the production of diallyl sulfide, a major volatile sulfur-containing compound. In the later stage, the effect of chrysin on alliin decomposition was minimal leading to 68.2% decomposition of alliin with the production of a mixture of diallyl sulfide, diallyl disulfide, and diallyl trisulfide. HMF greatly promoted the decomposition of alliin, resulting in almost 100% decomposition of alliin after 5 hours of reaction. Therefore, HMF could be deemed as a catalyst for the process.

Key words: chrysin, alliin, hydroxymethyl furfural (HMF), Maillard reaction

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