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• 成分分析 •    下一篇

不同年龄段乳粉的挥发性风味成分分析及其分类预测

姜子涛   

  1. 天津商业大学
  • 收稿日期:2021-08-08 修回日期:2022-05-05 出版日期:2022-08-25 发布日期:2022-08-19
  • 通讯作者: 姜子涛 E-mail:ztjiang@yahoo.com
  • 基金资助:
    天津市自然科学基金项目;天津市高等学校自然科学研究项目

Analysis and Classification Prediction of Volatile Flavor Components in Milk Powder for Different Age Groups

Zi-Tao Jiang   

  • Received:2021-08-08 Revised:2022-05-05 Online:2022-08-25 Published:2022-08-19
  • Contact: Zi-Tao Jiang E-mail:ztjiang@yahoo.com

摘要: 采用超快速气相电子鼻对婴幼儿、学生、成人和中老年人全脂乳粉共24 种样品的挥发性风味成分进行分析,并结合线性判别分析(linear discriminant analysis,LDA)及线性支持向量机(linear support vector machine,LSVM),对乳粉的香气特征进行分类预测。结果表明,4 个不同年龄段乳粉中共检测出54 种挥发性风味成分,其中37 种共同成分,主要为丙醛、丙酮、己醛和己酸等。丙酸甲酯、1-辛烯-3-酮只在婴幼儿乳粉中存在;(E,E)-2,4-癸二烯醛和γ-十一内酯是学生乳粉的特有成分;庚醛仅在成人乳粉中被检出;2-丁酮和苯甲醛仅在中老年人乳粉中含有。采用相对气味活性值评价及绘制的香气雷达图结果表明,共有23 种挥发性成分对乳粉贡献了香气,其中10 种为4 个年龄段乳粉共有的关键香气贡献化合物,且乳粉中共同香气为奶香味、蔬菜味、水果味、花香味、青草味、焦糖味、焦油味;另外,杏仁味为婴幼儿乳粉中特征香气。感官评价结果显示,学生、成人乳粉风味总体优于婴幼儿、中老年人乳粉,且与香气雷达图结果差异明显。LDA和LSVM对不同年龄段乳粉的分类、预测准确率分别为93.3%和94.2%。

关键词: 乳粉, 超快速气相电子鼻, 挥发性风味成分, 线性判别分析, 线性支持向量机

Abstract: The ultra-fast gas chromatography electronic nose (UFGC E-nose) was used to analysis the volatile flavor components of 24 samples of infant, student, adult and middle-aged and elderly whole milk powder. Combined with linear discriminant analysis (LDA) and linear support vector machine (LSVM), the kinds of milk powder were classified and predicted. The results showed that 54 volatile flavor components were detected in four different age groups, among which 37 common components were propionaldehyde, acetone, hexanal and caproic acid, etc. Methyl propionate and 1-octen-3-one only existed in infant milk powder. (E,E)-2,4-Decadienal and γ-unsecalactone were the special components of student milk powder. Heptanal was only detected in adult milk powder. 2-Butanone and benzaldehyde were only found in middle-aged and elderly milk powder. The results of relative odor activity value evaluation and aroma radar map showed that 23 volatile components contributed to the aroma, 10 of which were the key aroma contributing compounds shared by the four age groups, and the common aroma of milk powder were milk flavor, vegetable flavor, fruit flavor, flower flavor, grass flavor, caramel flavor and tar flavor. In addition, the almond flavor was the characteristic aroma of infant milk powder. The sensory evaluation results showed that the flavor of student milk powder and adult milk powder were better than that of infant milk powder and middle-aged and elderly milk powder, and there were significant differences with the results of aroma radar maps. The classification and prediction accuracy of LDA and LSVM for milk powder at different ages were 93.3% and 94.2%, respectively.

Key words: milk powder, ultra-fast gas chromatography electronic nose (UFGC E-nose), volatile flavor components, linear discriminant analysis (LDA), linear support vector machine (LSVM)

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