FOOD SCIENCE ›› 2013, Vol. 34 ›› Issue (22): 261-264.doi: 10.7506/spkx1002-6630-201322052
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GAO Feng,LIU Yan,KONG Wei-heng,CHENG Xi-ming,LI Jing,ZHANG Jie
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Abstract:
A method has been developed for the determination of chlorite, chlorate and perchlorate in carbonated beverage by using ion-chromatography-electrospray tandem mass spectrometry (IC-ESI-MS) in a negative ESI mode. Chlorite chlorate and perchlorate were separated on a high-capacity, hydroxide-selective column by gradient elution with KOH eluent generated from an eluent generator cartridge (EGC). The linear range was 1–200 ng/mL with a linear correlation coefficient of 0.997. The quantitation limits for chlorite, chlorate and perchlorate were 1.5, 1.0 μg/L and 0.6 μg/L, respectively. The recovery rates from spiked standard samples were in the range of 79%–104% with RSD in the range of 0.54%–4.49% (n = 6). This method proved to be simple, quick, sensitive and precise. It can be applied widely and suitable for simultaneous determination of chlorite chlorate and perchlorate in carbonated beverage.
Key words: IC-MS, carbonated beverage, chlorite, chlorate, perchlorate
CLC Number:
o657.63
GAO Feng,LIU Yan,KONG Wei-heng,CHENG Xi-ming,LI Jing,ZHANG Jie. Determination of Chlorite Chlorate and Perchlorate in Carbonated Beverage by Ion Chromatography-Electrospray Ionization Tandem Mass Spectrometry[J]. FOOD SCIENCE, 2013, 34(22): 261-264.
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URL: https://www.spkx.net.cn/EN/10.7506/spkx1002-6630-201322052
https://www.spkx.net.cn/EN/Y2013/V34/I22/261
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