Preparation of Graphene Oxide/CeO2-NiAl-Layered Double Hydroxide Composite for Cysteine Sensing

doi:10.7506/spkx1002-6630-201614025

Abstract

Abstract:

Graphene oxide/CeO2-NiAl-layered double hydroxide composite (GO/CeO2-NiAl-LDHs) was prepared using a
urea hydrolysis method and characterized by Fourier transform infrared (FT-IR) spectroscopy, X-Ray diffraction (XRD),
field emission scanning electron microscopy (FE-SEM) and electrochemical techniques. GO/CeO2-NiAl-LDHs showed good
electrochemical activity with an obvious layered structure. A sensor of L-cysteine (Cys) was fabricated using GO/CeO2-
NiAl-LDHs modified paraffin-impregnated graphite electrode (GO/CeO2-NiAl-LDHs/WGE). The oxidation peak currents
depending on the concentrations showed a good linear relationship in a range of 3 × 10-7 - 1 × 10-6 mol/L. The sensor could
be used for Cys sensing in real samples.

Key words: graphene oxide, layered double hydroxide, electrochemical determination, Cys

CLC Number:

TQ035

YUAN Aiguo, LI Bin, CHEN Jianping, JIN Guanping. Preparation of Graphene Oxide/CeO2-NiAl-Layered Double Hydroxide Composite for Cysteine Sensing[J]. FOOD SCIENCE, doi: 10.7506/spkx1002-6630-201614025.

References

[1] YU X Y, LIU Z G, HUANG X J. Nanostructured metal xides/

hydroxides-based electrochemical sensor for monitoring environmental

micropollutants[J]. Trends in Environmental Analytical Chemistry,

2014, 3/4: 28-35. DOI:10.1016/j.teac.2014.07.001.

[2] LAURA H, MARK E, PATRICK R, et al. Amperometric oxygen

sensor based on a platinum nanoparticle-modified polycrystalline

boron doped diamond disk electrode[J]. Analytical Chemistry, 2009,

81(3): 1023-1032. DOI:10.1021/ac8020906.

[3] YI Z, GUANG M Z, LIN T, et al. Electrochemical sensor based

on electrodeposited graphene-Au modified electrode and nanoAu

carrier a amplified signal strategy for attomolar mercury detection[J].

Analytical Chemistry, 2015, 87(2): 989-996. DOI:10.1021/ac503472p.

[4] RI Q, XIAO L, ZHANG R, et al. CuNi dendritic material: synthesis,

mechanism discussion, and application as glucose sensor[J]. Chemistry

of Materials, 2007, 19(17): 4174-4180. DOI:10.1021/cm070638a.

[5] TING Z, SILK L, JOACHIM K, et al. Effective electrochemistry of

human sulfite oxidase immobilized on quantum-dots-modified indium

tin oxide electrode[J]. ACS Applied Materials and Interfaces, 2015,

7(38): 21487-21494. DOI:10.1021/acsami.5b06665.

[6] ZHI P, XU G Q. Hydrothermal synthesis of layered double hydroxides

(LDHs) from mixed MgO and Al2O3: LDH formation mechanism[J].

Chemistry of Materials, 2005, 17(5): 1055-1062. DOI:10.1021/

cm048085g.

[7] KARTHIKEYAN K, SAMUTHIR A, YUN S L. LiMnBO3 nanobeads

as an innovative anode material for high power lithium ion capacitor

applications[J]. ACS Applied Materials and Interfaces, 2014, 6(14):

11357-11367. DOI:10.1021/am5019034.

[8] KULKARNI S B, JAGADALE A D, KUMBHAR V S, et al.

Potentiodynamic deposition of composition influenced Co1-xNix

LDHs thin film electrode for redox supercapacitors[J]. International

Journal of Hydrogen Energy, 2013, 38(10): 4046-4053. DOI:10.1016/

j.ijhydene.2013.01.047.

[9] BALIARSINGH N, PARIDA K M G C, PRADHAN G C. Effects of

Co, Ni, Cu, and Zn on photophysical and photocatalytic properties of

carbonate intercalated MII/Cr LDHs for enhanced photodegradation

of methyl orange[J]. Industrial and Engineering Chemistry

Research, 2014, 53(10): 3834-3841. DOI:10.1021/ie403769b.

[10] MANOJ R, MD H R, MOUNI R, et al. Solvent-adoptable polymer Ni/

NiCo alloy nanochains: highly active and versatile catalysts for various

organic reactions in both aqueous and nonaqueous media[J]. ACS

Applied Materials and Interfaces, 2012, 4(2): 878-889. DOI:10.1021/

am201549a.

[11] FRNG J, LIANG Z, SHUITRONG L, et al. Propane dehydrogenation

over Pt/TiO2-Al2O3 catalysts[J]. ACS Catalysis, 2015, 5(1): 438-447.

DOI:10.1021/cs501279v.

[12] GUZMAN J, CARRETTIN S, CORMA A. Spectroscopic evidence

for the supply of reactive oxygen during CO oxidation catalyzed by

gold supported on nanocrystalline CeO2[J]. Journal of the American

Chemical Society, 2005, 127(10): 3286-3287. DOI:10.1021/

ja043752s.

[13] ZHAO G, LI J, REN X, et al. Few-layered graphene oxide nanosheets

as superior sorbents for heavy metal ion pollution management[J].

Environmental Science and Technology, 2011, 45(24): 10454-10462.

DOI:10.1021/es203439v.

[14] SHARMA S K, JASRA R V. Synthesis of 2-ethylhexanal from

propylene in a single pot using an ecofriendly multifunctional

catalyst synthesized by intercalation of HRhCO(TPPTS)3 complex

in the interlayer space of hydrotalcite[J]. Industrial and Engineering

Chemistry Research, 2011, 50(5): 2815-2821. DOI:10.1021/

ie1015365.

[15] PINGUI T, XU X G, LIN Y J, et al. Enhancement of the thermo- and

photostability of an anionic dye by intercalation in a zinc-aluminum

layered double hydroxide host[J]. Industrial and Engineering

Chemistry Research, 2008, 47(8): 2478-2483. DOI:10.1021/

ie0710420.

[16] WANG W H, OLEKSANDR R, XU X Y, et al. Detection of

homocysteine and cysteine[J]. Journal of the American Chemical

Society, 2005, 127(45): 15949-15958. DOI:10.1021/ja054962n.

[17] HUMMERS W S J, OFFEMAN R E. Preparation of graphitic oxide[J].

Journal of the American Chemical Society, 1958, 80(6): 1339-1339.

DOI:10.1021/ja01539a017.

[18] NIU Y L, LI R Y, LI Z J, et al. High-performance supercapacitors

materials prepared via in situ growth of NiAl-layered double hydroxide

nanoflakes on well-activated graphene nanosheets[J]. Electrochimica

Acta, 2013, 94: 360-366. DOI:10.1016/j.electacta.2012.09.084.

[19] LEROUX F, MEDDAR L, MAILHOT B. Characterization and

photooxidative behaviour of nanocomposites formed with polystyrene

and LDHs organo-modified by monomer surfactant[J]. Polymer, 2005,

46(11): 3571-3578. DOI:10.1016/j.polymer.2005.03.044.

[20] RADHA A V, KAMATH P V, SHIVAKUMARA C. Mechanism of

the anion exchange reactions of the layered double hydroxides (LDHs)

of Ca and Mg with Al[J]. Solid State Sciences, 2005, 7(10): 1180-

1187. DOI:10.1016/j.solidstatesciences.2005.05.004.

[21] XU Q H, XU D M, GUAN M Y. ZnO/Al2O3/CeO2 composite with

enhanced gas sensing performance[J]. Sensors and Actuators B:

Chemical, 2013, 177: 1134-1141. DOI:10.1016/j.snb.2012.12.029.

[22] ZHANG T, LI Q, XIAO H. Enhanced fluoride removal from

water by non-thermal plasma modified CeO2/Mg-Fe layered

double hydroxides[J]. Applied Clay Science, 2013, 72: 117-123.

DOI:10.1016/j.clay.2012.12.003.

[23] WEI J, WANG J, SONG Y, et al. Synthesis of self-assembled layered

double hydroxides/carbon composites by in situ solvothermal method

and their application in capacitors[J]. Journal of Solid State Chemistry,

2012, 196: 175-181. DOI:10.1016/j.jssc.2012.06.009.

[24] SAKR A E, ZAKI T, SABER O, et al. Synthesis of Zn-Al LDHs

intercalated with urea derived anions for capturing carbon dioxide

from natural gas[J]. Journal of the Taiwan Institute of Chemical

Engineers, 2013, 44(6): 957-962. DOI:10.1016/j.jtice.2013.02.003.

[25] LIU B H, YU S H, CHEN S F, et al. Hexamethylenetetramine directed

synthesis and properties of a new family of α-nickel hydroxide

organic-inorganic hybrid materials with high chemical stability[J].

The Journal of Physical Chemistry B, 2006, 110(9): 4039-4046.

DOI:10.1021/jp055970t.

[26] 王万岭. 比色法测定胱氨酸片的含量[J]. 中国生化药物杂志, 2000,

21(6): 293-294. DOI:10.3969/j.issn.1005-1678.2000.06.009.