食品科学 ›› 2023, Vol. 44 ›› Issue (16): 127-134.doi: 10.7506/spkx1002-6630-20221115-175

• 食品化学 • 上一篇    下一篇

乳化剂和共乳化剂组成对亚麻籽油纳米乳液氧化稳定性的影响

田奕彤,李银汇,冯思敏   

  1. (浙江工业大学食品科学与工程学院,浙江 杭州 310014)
  • 出版日期:2023-08-25 发布日期:2023-09-01
  • 基金资助:
    浙江省重点研发项目(2021C02019);浙江省自然科学基金项目(LGD22C200001)

Effect of Emulsifier and Co-emulsifier Combination on Oxidation Stability of Flaxseed Oil Nanoemulsion

TIAN Yitong, LI Yinhui, FENG Simin   

  1. (College of Food Science and Technology, Zhejiang University of Technology, Hangzhou 310014, China)
  • Online:2023-08-25 Published:2023-09-01

摘要: 采用超声乳化法制备负载亚麻籽油的纳米乳液,旨在探讨辛烯基琥珀酸淀粉钠作为乳化剂和大豆分离蛋白(soy protein isolate,SPI)作为共乳化剂对纳米乳液氧化稳定性的影响。结果表明:最佳乳液制备工艺条件为超声功率600 W、芯壁比1∶1.5、脉冲模式8 s、超声时间20 min,该工艺条件下制备的纳米乳液具有高包封率((75.1±4.9)%~(74.6±4.2)%)、低粒径((244.0±3.0)~(246.8±4.5)nm)和高Zeta电位绝对值((-67.2±3.0)~(-69.3±4.0)mV)的特点。随着SPI的加入,纳米乳液的过氧化值、硫代巴比妥酸反应物值分别显著降低,氧化稳定性显著提高。这是因为,随着混合乳化剂疏水性的增加,亚麻籽油接触水相中氧自由基量显著降低。本研究为提高亚麻籽油的水溶性和氧化稳定性提供了一种新思路,为延长亚麻籽油货架期、促进其在食品领域的应用提供了理论基础。

关键词: 亚麻籽油;辛烯基琥珀酸淀粉钠;大豆分离蛋白;纳米乳液;超声乳化

Abstract: The purpose of this study was to investigate the effects of sodium starch octenyl succinate (SSOS) as emulsifier and soy protein isolate (SPI) as co-emulsifier on the oxidative stability of nanoemulsion. The ultrasonic emulsification method was used to prepare flaxseed oil nanoemulsion. The results showed that the optimum preparation conditions were as follows: ultrasonic power of 600 W, core-to-wall ratio of 1:1.5, pulse mode of 8 s, and ultrasonication time of 20 min. The nanoemulsion obtained under these conditions was characterized by high embedding rate ((75.1 ± 4.9)% to (74.6 ± 4.2)%), low particle size ((244.0 ± 3.0) to (246.8 ± 4.5) nm) and high absolute zeta-potential value ((−67.2 ± 3.0) to (−69.3 ± 4.0) mV). With the addition of SPI, the peroxide value (PV) and thiobarbituric acid reactive substances (TBARS) value of the nanoemulsion were significantly reduced, and the oxidative stability was remarkably improved. This could result from the fact that SPI could increase the hydrophobicity of the mixed emulsifier, preventing flaxseed oil from contacting with oxygen radicals in the aqueous phase. This study will provide a new idea for improving the water solubility and oxidative stability of flaxseed oil, and provide a theoretical basis for extending the shelf life of flaxseed oil and promoting its application in the food field.

Key words: flaxseed oil; sodium starch octenyl succinate; soy protein isolate; nanoemulsion; ultrasonic emulsification

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