食品科学 ›› 2018, Vol. 39 ›› Issue (20): 27-33.doi: 10.7506/spkx1002-6630-201820005

• 食品化学 • 上一篇    下一篇

加热条件下α-生育酚在油脂中的抗氧化活性、损耗及其对油脂全氧化值的影响

郭晓峰,毕艳兰*,陈佳丽   

  1. (河南工业大学粮油食品学院,河南?郑州 450001)
  • 出版日期:2018-10-25 发布日期:2018-10-24
  • 基金资助:
    国家自然科学基金面上项目(31671818)

Antioxidant Activity and Loss of α-Tocopherol and Its Effect on the Total Oxidation Value of Edible Oils and Fats under Heating Conditions

GUO Xiaofeng, BI Yanlan*, CHEN Jiali   

  1. (College of Food Science and Engineering, Henan University of Technology, Zhengzhou 450001, China)
  • Online:2018-10-25 Published:2018-10-24

摘要: 以大豆油、棕榈油、茶油和猪油为材料,以α-生育酚为研究对象,采用Rancimat法(110~130?℃)和烘箱法(120~180?℃)研究在加热条件下α-生育酚在油脂中的抗氧化活性、损耗情况及其对油脂全氧化值的影响。Rancimat结果表明:110 ℃条件下,α-生育酚(200~1?000?mg/kg)能显著延长猪油、茶油和棕榈油的氧化诱导期(P<0.05),且添加量越大,油脂的氧化诱导期越长,而在大豆油中,α-生育酚则表现出促氧化现象,即添加量越大,大豆油氧化诱导期越短;烘箱实验结果表明:α-生育酚在油脂中的损耗率,与加热温度呈正相关,与其添加量呈负相关;180?℃条件下,α-生育酚(1?000?mg/kg)能有效抑制大豆油、茶油和猪油在加热过程中全氧化值的增长;而在棕榈油中,α-生育酚促进了棕榈油全氧化值的增大,添加量越大,促进作用越强。

关键词: α-生育酚, 损耗, 抗氧化, 油脂, 加热

Abstract: In this study, the antioxidant activity of α-tocopherol in soybean oil, palm oil, tea seed oil (Camellia oleifera Abel.) and lard was investigated under Rancimat test (110–130 ℃) and oven heating (120–180 ℃) conditions. α-Tocopherol loss and its effect on the total oxidation value of oils and fats were determined as well. The Rancimat test results showed that the addition of α-tocopherol (200–1 000 mg/kg) could concentration dependently significantly prolong the induction period (IP) of lard, and tea seed oil at 110 ℃ (P < 0.05), while the IP of soybean oil was negatively correlated with the concentration of α-tocopherol added. The oven test results showed that α-tocopherol loss was positively correlated with the heating temperature but negatively correlated with α-tocopherol addition. α-Tocopherol (1 000 mg/kg) could inhibit the increase of total oxidation values (TV) of soybean oil, tea seed oil, and lard at 180 ℃. On the other hand, the addition of α-tocopherol (500–1 000 mg/kg) showed a pro-oxidant effect in palm oil.

Key words: α-tocopherol, loss, antioxidant activity, oils and fats, heating

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